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Nuclear Magnetic Resonance Spectroscopy. The Structure of Butenylmagnesium Bromide

Nordlander, J. Eric and Young, William G. and Roberts, John D. (1961) Nuclear Magnetic Resonance Spectroscopy. The Structure of Butenylmagnesium Bromide. Journal of the American Chemical Society, 83 (2). pp. 494-495. ISSN 0002-7863. doi:10.1021/ja01463a062.

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Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same butenyl Grignard reagent, which conceivably could be crotylmagnesium bromide (I), α-methylallyl-magnesium bromide (II), a more or less mobile equilibrium mixture of I and II, or an intermediate, bridged structure such as III.

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Additional Information:© 1961 American Chemical Society. Received December 12, 1960. Supported in part by the Office of Naval Research.
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Office of Naval Research (ONR)UNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry2649
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Official Citation:NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY. THE STRUCTURE OF BUTENYLMAGNESIUM BROMIDE J. Eric Nordlander, William G. Young, and John D. Roberts Journal of the American Chemical Society 1961 83 (2), 494-495 DOI: 10.1021/ja01463a062
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61318
Deposited By: Ruth Sustaita
Deposited On:20 Oct 2015 18:06
Last Modified:10 Nov 2021 22:47

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