Nordlander, J. Eric and Young, William G. and Roberts, John D. (1961) Nuclear Magnetic Resonance Spectroscopy. The Structure of Butenylmagnesium Bromide. Journal of the American Chemical Society, 83 (2). pp. 494-495. ISSN 0002-7863. doi:10.1021/ja01463a062. https://resolver.caltech.edu/CaltechAUTHORS:20151020-095617120
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Abstract
Crotyl bromide and α-methylallyl bromide each react with magnesium in ether to yield the same butenyl Grignard reagent, which conceivably could be crotylmagnesium bromide (I), α-methylallyl-magnesium bromide (II), a more or less mobile equilibrium mixture of I and II, or an intermediate, bridged structure such as III.
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| Additional Information: | © 1961 American Chemical Society. Received December 12, 1960. Supported in part by the Office of Naval Research. | |||||||||
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| Issue or Number: | 2 | |||||||||
| DOI: | 10.1021/ja01463a062 | |||||||||
| Record Number: | CaltechAUTHORS:20151020-095617120 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151020-095617120 | |||||||||
| Official Citation: | NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY. THE STRUCTURE OF BUTENYLMAGNESIUM BROMIDE J. Eric Nordlander, William G. Young, and John D. Roberts Journal of the American Chemical Society 1961 83 (2), 494-495 DOI: 10.1021/ja01463a062 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61318 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 20 Oct 2015 18:06 | |||||||||
| Last Modified: | 10 Nov 2021 22:47 |
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