Lutz, Raymond P. and Roberts, John D. (1961) Mechanism of the Diels-Alder Reaction. Journal of the American Chemical Society, 83 (9). pp. 2198-2200. ISSN 0002-7863. doi:10.1021/ja01470a039. https://resolver.caltech.edu/CaltechAUTHORS:20151020-105557319
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Abstract
The thermal interconversions of α- and β-1-hydroxydicyclopentadiene with syn- and anti-8-hydroxydicyclopentadiene, respectively, with retention of optical activity suggest that other Diels-Alder dimers might undergo analogous rearrangements. The conversions of S-ketodicyclopentadiene and a chlorinated derivative to the Species III might be the transition state or else an intermediate, but in either case its geometry is formulated as being highly restricted.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1961 American Chemical Society. Received March 11, 1961. Supported in part by the Office of Naval Research. | |||||||||
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| Issue or Number: | 9 | |||||||||
| DOI: | 10.1021/ja01470a039 | |||||||||
| Record Number: | CaltechAUTHORS:20151020-105557319 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151020-105557319 | |||||||||
| Official Citation: | MECHANISM OF THE DIELS-ALDER REACTION Raymond P. Lutz and John D. Roberts Journal of the American Chemical Society 1961 83 (9), 2198-2200 DOI: 10.1021/ja01470a039 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61323 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 20 Oct 2015 19:29 | |||||||||
| Last Modified: | 10 Nov 2021 22:47 |
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