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Small-Ring Compounds. XXXIII. A Study by Nuclear Magnetic Resonance of the Extent of Isotope-position Rearrangement in the Vapor-phase Photochlorination of methyl-^(13)C-Cyclopropane

Renk, E. and Shafer, Paul R. and Graham, W. H. and Mazur, R. H. and Roberts, John D. (1961) Small-Ring Compounds. XXXIII. A Study by Nuclear Magnetic Resonance of the Extent of Isotope-position Rearrangement in the Vapor-phase Photochlorination of methyl-^(13)C-Cyclopropane. Journal of the American Chemical Society, 83 (8). pp. 1987-1989. ISSN 0002-7863. doi:10.1021/ja01469a049. https://resolver.caltech.edu/CaltechAUTHORS:20151020-105558215

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Abstract

Vapor-phase photochlorination of methyl-^(13)C-cyclopropane was found to yield cyclopropylcarbinyl-α-^(13)C chloride and allyl-γ-^(13)C-carbinyl chloride. Within the experimental error of the analytical method (nuclear magnetic resonance spectroscopy), no other ^(13)C-position isomers of the chlorides were formed.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01469a049DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01469a049PublisherArticle
Additional Information:© 1961 American Chemical Society. Received December 14, 1960. Supported in part by the Office of Naval Research, the Petroleum Research Fund of the American Chemical Society, and the National Science Foundation. Grateful acknowledgment is hereby made to the donors of the Petroleum Research Fund. National Science Foundation Faculty Fellow, 1959-1960.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
American Chemical Society Petroleum Research FundUNSPECIFIED
NSFUNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry2646
Issue or Number:8
DOI:10.1021/ja01469a049
Record Number:CaltechAUTHORS:20151020-105558215
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151020-105558215
Official Citation:Small-Ring Compounds. XXXIII. A Study by Nuclear Magnetic Resonance of the Extent of Isotope-position Rearrangement in the Vapor-phase Photochlorination of methyl-13C-Cyclopropane E. Renk, Paul R. Shafer, W. H. Graham, R. H. Mazur, and John D. Roberts Journal of the American Chemical Society 1961 83 (8), 1987-1989 DOI: 10.1021/ja01469a049
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61324
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:20 Oct 2015 18:20
Last Modified:10 Nov 2021 22:47

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