Nordlander, J. Eric and Roberts, John D. (1959) Nuclear Magnetic Resonance Spectra. Allylmagnesium Bromide. Journal of the American Chemical Society, 81 (7). pp. 1769-1770. ISSN 0002-7863. doi:10.1021/ja01516a066. https://resolver.caltech.edu/CaltechAUTHORS:20151020-141342444
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Abstract
The proton nuclear magnetic resonance (n.m.r.) spectrum of allylmagnesium bromide (I, Fig. 1) Fig. 1.-Proton magnetic resonance spectra of allylmagnesium bromide in diethyl ether solution (upper) and allylbenzene (lower). The spectra were taken with a Varian Associates High Resolution Spectrometer (V-4300) at 60 Mc. with a 12-inch magnet equipped with a Super-stabilizer. Chemical shifts are in C.P.S. from benzene (external reference) and were measured by the audio-oscillator sideband superposition method. The signals designated C_6H_(10) in the allylmagnesium bromide spectrum are due to diallyl formed by coupling during preparation of the Grignard reagent, as verified by the spectrum of a sample to which diallyl had been added deliberately.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1959 American Chemical Society. Received February 26, 1959. Supported in part by the Office of Naval Research. | |||||||||
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| Issue or Number: | 7 | |||||||||
| DOI: | 10.1021/ja01516a066 | |||||||||
| Record Number: | CaltechAUTHORS:20151020-141342444 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151020-141342444 | |||||||||
| Official Citation: | NUCLEAR MAGNETIC RESONANCE SPECTRA. ALLYLMAGNESIUM BROMIDE J. Eric Nordlander and John D. Roberts Journal of the American Chemical Society 1959 81 (7), 1769-1770 DOI: 10.1021/ja01516a066 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61340 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 20 Oct 2015 22:38 | |||||||||
| Last Modified: | 10 Nov 2021 22:47 |
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