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Nuclear Magnetic Resonance Spectra. Allylmagnesium Bromide

Nordlander, J. Eric and Roberts, John D. (1959) Nuclear Magnetic Resonance Spectra. Allylmagnesium Bromide. Journal of the American Chemical Society, 81 (7). pp. 1769-1770. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20151020-141342444

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Abstract

The proton nuclear magnetic resonance (n.m.r.) spectrum of allylmagnesium bromide (I, Fig. 1) Fig. 1.-Proton magnetic resonance spectra of allylmagnesium bromide in diethyl ether solution (upper) and allylbenzene (lower). The spectra were taken with a Varian Associates High Resolution Spectrometer (V-4300) at 60 Mc. with a 12-inch magnet equipped with a Super-stabilizer. Chemical shifts are in C.P.S. from benzene (external reference) and were measured by the audio-oscillator sideband superposition method. The signals designated C_6H_(10) in the allylmagnesium bromide spectrum are due to diallyl formed by coupling during preparation of the Grignard reagent, as verified by the spectrum of a sample to which diallyl had been added deliberately.


Item Type:Article
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http://dx.doi.org/10.1021/ja01516a066DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01516a066PublisherArticle
Additional Information:© 1959 American Chemical Society. Received February 26, 1959. Supported in part by the Office of Naval Research.
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Office of Naval Research (ONR)UNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry2442
Record Number:CaltechAUTHORS:20151020-141342444
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151020-141342444
Official Citation:NUCLEAR MAGNETIC RESONANCE SPECTRA. ALLYLMAGNESIUM BROMIDE J. Eric Nordlander and John D. Roberts Journal of the American Chemical Society 1959 81 (7), 1769-1770 DOI: 10.1021/ja01516a066
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61340
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:20 Oct 2015 22:38
Last Modified:20 Oct 2015 22:38

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