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Small-ring Compounds. XX. 1,3-Dimethylenecyclobutane and Related Compounds

Caserio, Frederick F., Jr. and Parker, Stuart H. and Piccolini, Richard and Roberts, John D. (1958) Small-ring Compounds. XX. 1,3-Dimethylenecyclobutane and Related Compounds. Journal of the American Chemical Society, 80 (20). pp. 5507-5513. ISSN 0002-7863. doi:10.1021/ja01553a049.

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1,3-Dimethylenecyclobutane and 1-methyl-3-methylenecyclobutene have been synthesized by way of 3-methylenecyclobutanecarboxylic acid and (3-methylenecyclobutylcarbinyl)-dimethylamine. No clear experimental evidence was obtained for π-type electronic interaction across the ring of 1,3-dimethylenecyclobutane.

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Additional Information:© 1958 American Chemical Society. Received May 2, 1958. Supported in part by the Petroleum Research Fund of the American Chemical Society. Grateful acknowledgment is hereby made to the Donors of this Fund. Fellow of the Foreign Research Scientists Program, 1954-1956.
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American Chemical Society Petroleum Research FundUNSPECIFIED
Foreign Research Scientists ProgramUNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry2316
Issue or Number:20
Record Number:CaltechAUTHORS:20151020-141345078
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Official Citation:Small-ring Compounds. XX. 1,3-Dimethylenecyclobutane and Related Compounds Frederick F. Caserio Jr., Stuart H. Parker, Richard Piccolini, and John D. Roberts Journal of the American Chemical Society 1958 80 (20), 5507-5513 DOI: 10.1021/ja01553a049
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61343
Deposited By: Ruth Sustaita
Deposited On:20 Oct 2015 22:30
Last Modified:10 Nov 2021 22:47

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