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Anomalous Spin-Spin Splitting in Nuclear Magnetic Resonance Spectra of Cyclobutenes

Sharts, Clay M. and Roberts, John D. (1957) Anomalous Spin-Spin Splitting in Nuclear Magnetic Resonance Spectra of Cyclobutenes. Journal of the American Chemical Society, 79 (4). p. 1008. ISSN 0002-7863. doi:10.1021/ja01561a072.

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A spectacular failure of F-F spin-spin coupling constants, A_(ij), to decrease monotonically with the number of chemical bonds separating nuclei i and j has been deduced from the nuclear magnetic resonance (n.m.r.) spectrum of perfluorodimethylethylamine. The current importance attached to the use of n.m.r. spectra as a tool for establishment of organic structures prompts us to report a number of similarly anomalous H-F spin-spin coupling constants in cyclobutene derivatives.

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Additional Information:© 1957 American Chemical Society. Received January 24, 1957. We are indebted to Drs. Y. Kitahara, R. E. Krall, E. F. Silversmith, E. J. Smutny, and Mr. S. Manatt for samples of many. This work was supported in part by the Office of Naval Research.
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Office of Naval Research (ONR)UNSPECIFIED
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Caltech Gates and Crellin Laboratories of Chemistry2074
Issue or Number:4
Record Number:CaltechAUTHORS:20151021-100828582
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Official Citation:ANOMALOUS SPIN-SPIN SPLITTING IN NUCLEAR MAGNETIC RESONANCE SPECTRA OF CYCLOBUTENES Clay M. Sharts and John D. Roberts Journal of the American Chemical Society 1957 79 (4), 1008-1008 DOI: 10.1021/ja01561a072
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ID Code:61367
Deposited On:21 Oct 2015 19:02
Last Modified:10 Nov 2021 22:48

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