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Small-Ring Compounds. XIII. The Mechanism of Racemization of Optically Active 2,4-Dichloro-3-phenylcyclobutenone

Jenny, Erwin F. and Roberts, John D. (1956) Small-Ring Compounds. XIII. The Mechanism of Racemization of Optically Active 2,4-Dichloro-3-phenylcyclobutenone. Journal of the American Chemical Society, 78 (9). pp. 2005-2009. ISSN 0002-7863. doi:10.1021/ja01590a068. https://resolver.caltech.edu/CaltechAUTHORS:20151021-112215086

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Abstract

Racemization of optically active 2,4-dichloro-3-phenylcyclobutenone has been shown to involve reversible formation of (1-phenyl-2-chloroethenyl)-chloroketene 2,4-dichloro-3-phenyl-3-butenoic acid yields 2,4-dichloro-3-phenylcyclobutenone on treatment with acetic anhydride.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01590a068DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01590a068PublisherArticle
Additional Information:© 1956 American Chemical Society. Received August 29, 1955. Presented at the 14th National Organic Symposium of the American Chemical Society, Lafayette, Ind, June 14, 1955. Arthur Amos Noyes Fellow, 1954-1955.
Funders:
Funding AgencyGrant Number
Caltech Arthur A. Noyes FellowshipUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Gates and Crellin Laboratories of Chemistry2029
Issue or Number:9
DOI:10.1021/ja01590a068
Record Number:CaltechAUTHORS:20151021-112215086
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151021-112215086
Official Citation:Small-Ring Compounds. XIII. The Mechanism of Racemization of Optically Active 2,4-Dichloro-3-phenylcyclobutenone Erwin F. Jenny and John D. Roberts Journal of the American Chemical Society 1956 78 (9), 2005-2009 DOI: 10.1021/ja01590a068
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61378
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:21 Oct 2015 20:06
Last Modified:10 Nov 2021 22:48

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