Smutny, Edgar J. and Roberts, John D. (1955) Phenylcyclobutadienoquinone. Journal of the American Chemical Society, 77 (12). p. 3420. ISSN 0002-7863. doi:10.1021/ja01617a096. https://resolver.caltech.edu/CaltechAUTHORS:20151021-142338379
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Abstract
No authentic cylobutadiene derivatives appear to have yet been prepared except for biphenylene and related substances, where the four-membered rings are part of fused-ring system. The failure to detect cyclobutadiene or its non-fused ring derivatives among the products of appropriate synthetic reactions can be ascribed either to excessive ring strain or unfavorable electronic configurations. Strong evidence that ring strain is not the most important factor is now provided by a synthesis of the quite stable (phenylcyclobutadienoquinone (phenylcyclobutendione, I) which to a first approximation is expected to have the same degree of ring strain as phenylcyclobutadiene.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1955 American Chemical Society. Received May 20, 1955. | |||||||||
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| Issue or Number: | 12 | |||||||||
| DOI: | 10.1021/ja01617a096 | |||||||||
| Record Number: | CaltechAUTHORS:20151021-142338379 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151021-142338379 | |||||||||
| Official Citation: | PHENYLCYCLOBUTADIENOQUINONE Edgar J. Smutny and John D. Roberts Journal of the American Chemical Society 1955 77 (12), 3420-3420 DOI: 10.1021/ja01617a096 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61393 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 22 Oct 2015 18:23 | |||||||||
| Last Modified: | 10 Nov 2021 22:48 |
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