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Further Investigation of the Solvolytic Reactivity of Nortricyclyl, Dehydronorbornyl and Norbornyl Halides

Roberts, John D. and Bennett, W. (1954) Further Investigation of the Solvolytic Reactivity of Nortricyclyl, Dehydronorbornyl and Norbornyl Halides. Journal of the American Chemical Society, 76 (18). pp. 4623-4624. ISSN 0002-7863. doi:10.1021/ja01647a041. https://resolver.caltech.edu/CaltechAUTHORS:20151021-142339584

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Abstract

In a previous paper, we reported solvolytic reactivities in 80% ethanol-20% water (by volume) of nortricyclyl (I), endo-dehydronorbornyl (II), exo-dehydronorbornyl (III), endo-norbornyl (IV) and exo-norbornyl (V) halides. In subsequent publications, it was shown that the ratios of the reactivities of the exo-compounds II and IV to those of the exo-compounds III and V are much greater with the p-bromobenzenesulfonates than reported for the corresponding halides.


Item Type:Article
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http://dx.doi.org/10.1021/ja01647a041DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01647a041PublisherArticle
Additional Information:© 1954 American Chemical Society. Received April 23, 1954. Supported in part by the program of research of the U. S. Atomic Energy Commission under Contract AT(30-1)-905.
Funders:
Funding AgencyGrant Number
Atomic Energy CommissionAT(30-1)-905
Issue or Number:18
DOI:10.1021/ja01647a041
Record Number:CaltechAUTHORS:20151021-142339584
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151021-142339584
Official Citation:Further Investigation of the Solvolytic Reactivity of Nortricyclyl, Dehydronorbornyl and Norbornyl Halides John D. Roberts and W. Bennett Journal of the American Chemical Society 1954 76 (18), 4623-4624 DOI: 10.1021/ja01647a041
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61397
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:22 Oct 2015 18:21
Last Modified:10 Nov 2021 22:48

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