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Kinetics and Some Hydrogen Isotope Effects of the Reaction of Diphenyldiazomethane with Acetic Acid in Ethanol

Roberts, John D. and Regan, Clare M. (1952) Kinetics and Some Hydrogen Isotope Effects of the Reaction of Diphenyldiazomethane with Acetic Acid in Ethanol. Journal of the American Chemical Society, 74 (14). pp. 3695-3696. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20151022-140102651

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Abstract

As part of other investigations, we have had occasion to study the kinetics and hydrogen isotope effects of the reaction of diphenyldiazomethane with acetic acid in ethanol using the techniques previously developed for other carboxylic acids. As might be expected, the reaction of acetic acid with diphenyldiazomethane is very similar to that with benzoic acid in that it is accuratery first order in acid as well diazo compound and shows similar salt and medium effects (cf. Table I).


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URLURL TypeDescription
http://dx.doi.org/10.1021/ja01134a510DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01134a510PublisherArticle
Additional Information:© 1952 American Chemical Society. Received December 3, 1951. Supported in part by the program of research of the United States Atomic Energy Commission.
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Funding AgencyGrant Number
Atomic Energy CommissionUNSPECIFIED
Issue or Number:14
Record Number:CaltechAUTHORS:20151022-140102651
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151022-140102651
Official Citation:Kinetics and Some Hydrogen Isotope Effects of the Reaction of Diphenyldiazomethane with Acetic Acid in Ethanol John D. Roberts and Clare M. Regan Journal of the American Chemical Society 1952 74 (14), 3695-3696 DOI: 10.1021/ja01134a510
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61438
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:26 Oct 2015 21:47
Last Modified:03 Oct 2019 09:08

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