Roberts, John D. (1979) Aspects of the determination of equilibration rates by NMR spectroscopy. Pure and Applied Chemistry, 51 (5). pp. 1037-1047. ISSN 0033-4545. doi:10.1351/pac197951051037,. https://resolver.caltech.edu/CaltechAUTHORS:20151023-101623597
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Abstract
The origins of the line-shape method for determining the rates of chemical and conformational equilibration by NMR spectroscopy are reviewed for the purpose of illustrating the factors which should be considered in obtaining accurate rate data by this very useful technique. Besides a number of illustrations of how changes in rates of conformational equilibration change NMR spectra taken from the literature, some new results using a simple and direct procedure for measurement of NH exchange rates of amides and hydrazines by natural abundance ^(15)N NMR will be presented.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1979 Pergamon Press Ltd. IUPAC. Supported by the National Science Foundation and the Public Health Service, Research Grant No. GM-11072 from the Division of General Medical Sciences. | |||||||||
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| Issue or Number: | 5 | |||||||||
| DOI: | 10.1351/pac197951051037, | |||||||||
| Record Number: | CaltechAUTHORS:20151023-101623597 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151023-101623597 | |||||||||
| Official Citation: | Roberts, J. (2009). Aspects of the determination of equilibration rates by NMR spectroscopy. Pure and Applied Chemistry, 51(5), pp. 1037-1047. doi:10.1351/pac197951051037 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61477 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | INVALID USER | |||||||||
| Deposited On: | 26 Oct 2015 21:29 | |||||||||
| Last Modified: | 10 Nov 2021 22:49 |
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