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Internal-return rearrangement in solvolysis of cyclopropylcarbinyl derivatives

Servis, Kenneth L. and Roberts, John D. (1967) Internal-return rearrangement in solvolysis of cyclopropylcarbinyl derivatives. Tetrahedron Letters, 8 (15). pp. 1369-1372. ISSN 0040-4039.

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The unusual reactivities of cyclopropylcarbinyl derivatives in solvolytic reactions have led to a continuing interest in the details of the reaction mechanism and the structures of the intermediates (1). Conductimetric (2) and titrimetric (3) methods for the rate determinations have increased the precision of the measured rate constants but reliance on kinetic data alone has led to some interpretative oversights.

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Additional Information:© 1967 Pergamon Press Ltd. Received 30 January 1967. This work was supported in part by the National Science Foundation.
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Caltech Gates and Crellin Laboratories of Chemistry3470
Issue or Number:15
Record Number:CaltechAUTHORS:20151026-114005600
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Official Citation:Kenneth L. Servis, John D. Roberts, Internal-return rearrangement in solvolysis of cyclopropylcarbinyl derivatives, Tetrahedron Letters, Volume 8, Issue 15, 1967, Pages 1369-1372, ISSN 0040-4039, (
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61522
Deposited By: Ruth Sustaita
Deposited On:26 Oct 2015 21:54
Last Modified:03 Oct 2019 09:09

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