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The dissociation constants of methyl alkyl ketone cyanohydrins

Servis, Kenneth L. and Oliver, Lawrence K. and Roberts, John D. (1965) The dissociation constants of methyl alkyl ketone cyanohydrins. Tetrahedron, 21 (7). pp. 1827-1832. ISSN 0040-4020. http://resolver.caltech.edu/CaltechAUTHORS:20151026-114006150

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Abstract

The dissociation constants of a series of methyl alkyl ketone cyanohydrins have been measured by NMR spectroscopy. The heats of solutions of the ketones and the cyanohydrins have been determined. The effect of alkyl groups on the heats of solution have been shown to be unimportant in determining the observed dissociation constants of the cyanohydrins of these ketones.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/S0040-4020(01)98653-3DOIArticle
http://www.sciencedirect.com/science/article/pii/S0040402001986533PublisherArticle
Additional Information:© 1965 Pergamon Press Ltd. Received 5 November 1964; in revised form 21 January 1965. Supported in part by the National Science Foundation.
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Caltech Gates and Crellin Laboratories of Chemistry3164
Record Number:CaltechAUTHORS:20151026-114006150
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151026-114006150
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61524
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:26 Oct 2015 21:52
Last Modified:26 Oct 2015 21:52

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