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The dissociation constants of methyl alkyl ketone cyanohydrins

Servis, Kenneth L. and Oliver, Lawrence K. and Roberts, John D. (1965) The dissociation constants of methyl alkyl ketone cyanohydrins. Tetrahedron, 21 (7). pp. 1827-1832. ISSN 0040-4020. doi:10.1016/S0040-4020(01)98653-3.

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The dissociation constants of a series of methyl alkyl ketone cyanohydrins have been measured by NMR spectroscopy. The heats of solutions of the ketones and the cyanohydrins have been determined. The effect of alkyl groups on the heats of solution have been shown to be unimportant in determining the observed dissociation constants of the cyanohydrins of these ketones.

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Additional Information:© 1965 Pergamon Press Ltd. Received 5 November 1964; in revised form 21 January 1965. Supported in part by the National Science Foundation.
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Caltech Gates and Crellin Laboratories of Chemistry3164
Issue or Number:7
Record Number:CaltechAUTHORS:20151026-114006150
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61524
Deposited On:26 Oct 2015 21:52
Last Modified:10 Nov 2021 22:50

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