Howden, M. E. H. and Roberts, John D. (1963) Small-ring compounds—XXXVIII: Calculations of the relative stabilities of intermediates in the interconversion reactions of cyclopropylcarbinyl, cyclobutyl, and allylcarbinyl derivatives by the LCAO method. Tetrahedron, 19 (S 2). pp. 403-414. ISSN 0040-4020. doi:10.1016/S0040-4020(63)80029-0. https://resolver.caltech.edu/CaltechAUTHORS:20151026-142340213
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Abstract
The simple LCAO method with corrections for angle strain indicates that bicyclobutonium cations are likely to be more stable than homoallylic cations. The reverse is predicted to be true for the corresponding free-radical and anionic derivatives. The results are in accord with experiment.
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| Additional Information: | © 1963 Pergamon Press Ltd. Received 3 January 1962. Supported in part by the National Science Foundation; Contribution No. 2788 from the Gates and Crellin Laboratories of Chemistry, California Institute of Technology, Pasadena, California. | |||||||||
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| Issue or Number: | S 2 | |||||||||
| DOI: | 10.1016/S0040-4020(63)80029-0 | |||||||||
| Record Number: | CaltechAUTHORS:20151026-142340213 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151026-142340213 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61526 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 26 Oct 2015 22:23 | |||||||||
| Last Modified: | 10 Nov 2021 22:50 |
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