Arasaki, Yasuki and Takatsuka, Kazuo and Wang, Kwanghsi and McKoy, Vincent (2003) Pump-Probe Photoionization Study of the Passage and Bifurcation of a Quantum Wave Packet Across an Avoided Crossing. Physical Review Letters, 90 (24). Art. No. 248303. ISSN 0031-9007. doi:10.1103/PhysRevLett.90.248303. https://resolver.caltech.edu/CaltechAUTHORS:20151027-154126138
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Abstract
The application of femtosecond pump-probe photoelectron spectroscopy to directly observe vibrational wave packets passing through an avoided crossing is investigated using quantum wave packet dynamics calculations. Transfer of the vibrational wave packet between diabatic electronic surfaces, bifurcation of the wave packet, and wave packet construction via nonadiabatic mixing are shown to be observable as time-dependent splittings of peaks in the photoelectron spectra.
| Item Type: | Article | |||||||||
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| Additional Information: | © 2003 American Physical Society. (Received 26 November 2002; published 19 June 2003) This work has been supported in part by a Grant-in-Aid for the 21st Century COE Program for Frontiers in Fundamental Chemistry from the Ministry of Education, Culture, Sports, Science and Technology (Japan), by the Mitsubishi Foundation, and by the National Science Foundation (U.S.A.). | |||||||||
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| Issue or Number: | 24 | |||||||||
| Classification Code: | PACS numbers: 82.20.Gk, 33.60.–q, 82.53.Eb, 82.53.Kp | |||||||||
| DOI: | 10.1103/PhysRevLett.90.248303 | |||||||||
| Record Number: | CaltechAUTHORS:20151027-154126138 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151027-154126138 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61597 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 28 Oct 2015 18:40 | |||||||||
| Last Modified: | 10 Nov 2021 22:51 |
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