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Benzyn-Zwischenprodukte in der nukleophilen aromatischen Substitution

Jenny, Erwin F. and Caserio, Marjorie C. and Roberts, John D. (1958) Benzyn-Zwischenprodukte in der nukleophilen aromatischen Substitution. Experientia, 14 (10). pp. 349-354. ISSN 0014-4754. https://resolver.caltech.edu/CaltechAUTHORS:20151028-101337818

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Abstract

Many substitution reactions of aromatic halides, such as amination with metallic amides in ammonia or amine solutions, high-temperature alkaline hydrolyses and arylation with phenyllithium, lead to the formation of rearrangement products as the result of a common reaction path involving unstable ‘benzyne’ intermediates. The chemical evidence in favor of this reaction mechanism is discussed as are correlations of observed product compositions and applications to practical synthetic procedures.


Item Type:Article
Related URLs:
URLURL TypeDescription
http:dx.doi.org/10.1007/2FBF02159149DOIArticle
http://link.springer.com/article/10.1007%2FBF02159149PublisherArticle
Additional Information:© 1958 Springer.
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Gates and Crellin Laboratories of Chemistry2390
Issue or Number:10
Record Number:CaltechAUTHORS:20151028-101337818
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151028-101337818
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61631
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:28 Oct 2015 17:25
Last Modified:03 Oct 2019 09:10

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