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Benzyn-Zwischenprodukte in der nukleophilen aromatischen Substitution

Jenny, Erwin F. and Caserio, Marjorie C. and Roberts, John D. (1958) Benzyn-Zwischenprodukte in der nukleophilen aromatischen Substitution. Experientia, 14 (10). pp. 349-354. ISSN 0014-4754. doi:10.1007/2FBF02159149.

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Many substitution reactions of aromatic halides, such as amination with metallic amides in ammonia or amine solutions, high-temperature alkaline hydrolyses and arylation with phenyllithium, lead to the formation of rearrangement products as the result of a common reaction path involving unstable ‘benzyne’ intermediates. The chemical evidence in favor of this reaction mechanism is discussed as are correlations of observed product compositions and applications to practical synthetic procedures.

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Additional Information:© 1958 Springer.
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Caltech Gates and Crellin Laboratories of Chemistry2390
Issue or Number:10
Record Number:CaltechAUTHORS:20151028-101337818
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61631
Deposited By: Ruth Sustaita
Deposited On:28 Oct 2015 17:25
Last Modified:10 Nov 2021 22:51

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