Yavari, Issa and Staral, John S. and Roberts, John D. (1979) Nitrogen-15 Nuclear Magnetic Resonance Spectra of Isocyanates, Isothiocyanates and N-Sulfinylamines. Organic Magnetic Resonance, 12 (6). pp. 340-342. ISSN 0030-4921. doi:10.1002/mrc.1270120603. https://resolver.caltech.edu/CaltechAUTHORS:20151029-113928967
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Abstract
The ^(15)N NMR spectra of ten isocyanates, four isothiocyanates, and four N-sulfinylamines have been obtained at the natural-abundance level by high-resolution NMR spectroscopy. The results show that isocyanates and isothiocyanates have ^(15)N chemical shifts over 200 ppm toward higher fields compared to those of N-sulfinylamines. The sensitivity of the ^(15)N shifts in these substances to substituent and electronic effects are discussed.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1979 Heyden & Son Ltd. Received 6 June 1978; accepted 21 July 1978. This research was supported by the Public Health Service, Grant No. GM-11072 from the Division of General Medical Sciences, and by the National Science Foundation. | |||||||||
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| Issue or Number: | 6 | |||||||||
| DOI: | 10.1002/mrc.1270120603 | |||||||||
| Record Number: | CaltechAUTHORS:20151029-113928967 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151029-113928967 | |||||||||
| Official Citation: | Yavari, I., Staral, J. S. and Roberts, J. D. (1979), Nitrogen-15 nuclear magnetic resonance spectra of isocyanates, isothiocyanates and N-sulfinylamines. Org. Magn. Reson., 12: 340–342. doi: 10.1002/mrc.1270120603 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 61713 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | INVALID USER | |||||||||
| Deposited On: | 29 Oct 2015 18:48 | |||||||||
| Last Modified: | 10 Nov 2021 22:52 |
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