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Nitrogen-15 Nuclear Magnetic Resonance Spectra of Isocyanates, Isothiocyanates and N-Sulfinylamines

Yavari, Issa and Staral, John S. and Roberts, John D. (1979) Nitrogen-15 Nuclear Magnetic Resonance Spectra of Isocyanates, Isothiocyanates and N-Sulfinylamines. Organic Magnetic Resonance, 12 (6). pp. 340-342. ISSN 0030-4921. http://resolver.caltech.edu/CaltechAUTHORS:20151029-113928967

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Abstract

The ^(15)N NMR spectra of ten isocyanates, four isothiocyanates, and four N-sulfinylamines have been obtained at the natural-abundance level by high-resolution NMR spectroscopy. The results show that isocyanates and isothiocyanates have ^(15)N chemical shifts over 200 ppm toward higher fields compared to those of N-sulfinylamines. The sensitivity of the ^(15)N shifts in these substances to substituent and electronic effects are discussed.


Item Type:Article
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http://dx.doi.org/10.1002/mrc.1270120603DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/mrc.1270120603/abstractPublisherArticle
Additional Information:© 1979 Heyden & Son Ltd. Received 6 June 1978; accepted 21 July 1978. This research was supported by the Public Health Service, Grant No. GM-11072 from the Division of General Medical Sciences, and by the National Science Foundation.
Funders:
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U.S. Public Health Service (USPHS)GM-11072
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Caltech Gates and Crellin Laboratories of Chemistry5795
Record Number:CaltechAUTHORS:20151029-113928967
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151029-113928967
Official Citation:Yavari, I., Staral, J. S. and Roberts, J. D. (1979), Nitrogen-15 nuclear magnetic resonance spectra of isocyanates, isothiocyanates and N-sulfinylamines. Org. Magn. Reson., 12: 340–342. doi: 10.1002/mrc.1270120603
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61713
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:29 Oct 2015 18:48
Last Modified:29 Oct 2015 18:48

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