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Characterization of the heavy products of coal pyrolysis

Gavalas, George R. and Oka, Mitsuo (1978) Characterization of the heavy products of coal pyrolysis. Fuel, 57 (5). pp. 285-288. ISSN 0016-2361 . https://resolver.caltech.edu/CaltechAUTHORS:20151105-083250561

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Abstract

In order to obtain information about the production mechanism of large molecules in coal pyrolysis, a subbituminous and two bituminous coals were heated at 500° C for 30s under vacuum. The heavy products were dissolved in tetrahydrofuran (THF) and analysed by ^1H n.m.r. spectroscopy and gel-permeation chromatography in an atmospheric-pressure column. Parallel GPC, ^1H n.m.r. and ^(13)C n.m.r. studies were conducted with THF extracts of the same coals. The results are combined with elemental analysis data to obtain structural parameters of the extracts and pyrolysates.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0016-2361(78)90005-4DOIArticle
http://www.sciencedirect.com/science/article/pii/0016236178900054PublisherArticle
ORCID:
AuthorORCID
Gavalas, George R.0000-0003-1468-6835
Additional Information:© 1978 IPC Business Press. Received 9 May 1977. This research was supported by the National Science Foundation under Grant No. AER 74-12161.
Funders:
Funding AgencyGrant Number
NSFAER 74-12161
Issue or Number:5
Record Number:CaltechAUTHORS:20151105-083250561
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151105-083250561
Official Citation:George R. Gavalas, Mitsuo Oka, Characterization of the heavy products of coal pyrolysis, Fuel, Volume 57, Issue 5, May 1978, Pages 285-288, ISSN 0016-2361, http://dx.doi.org/10.1016/0016-2361(78)90005-4. (http://www.sciencedirect.com/science/article/pii/0016236178900054)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61878
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:06 Nov 2015 20:20
Last Modified:03 Oct 2019 09:12

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