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Kinetics of Dialin Thermolysis

Allen, D. T. and Gavalas, G. R. (1983) Kinetics of Dialin Thermolysis. International Journal of Chemical Kinetics, 15 (3). pp. 219-233. ISSN 0538-8066. https://resolver.caltech.edu/CaltechAUTHORS:20151105-105158432

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Abstract

The liquid-phase thermolysis of 1,2-dihydronaphthalene was studied in a batch reactor in the range of 350–400°C. The measured product distributions were in good agreement with calculations based on a free-radical scheme with rate constants estimated by thermochemical methods. The kinetic calculations were carried out by numerical integration and by the long-chain approximation (LCA), which yielded a closed-form solution.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/kin.550150303DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/kin.550150303/abstractPublisherArticle
ORCID:
AuthorORCID
Gavalas, G. R.0000-0003-1468-6835
Additional Information:© 1983 John Wiley & Sons, Inc. Received May 12, 1982. Accepted August 30, 1982.
Issue or Number:3
Record Number:CaltechAUTHORS:20151105-105158432
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151105-105158432
Official Citation:Allen, D. T. and Gavalas, G. R. (1983), Kinetics of dialin thermolysis. Int. J. Chem. Kinet., 15: 219–233. doi: 10.1002/kin.550150303
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:61893
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:06 Nov 2015 20:11
Last Modified:03 Oct 2019 09:13

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