Wang, Kwanghsi and Stephens, J. A. and McKoy, V. (1994) Studies of photoionization dynamics of methylidyne, imidogen, and hydroxyl radicals at near-threshold photoelectron kinetic energies. Journal of Physical Chemistry, 98 (2). pp. 460-466. ISSN 0022-3654. https://resolver.caltech.edu/CaltechAUTHORS:20151110-111102505
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Abstract
We discuss results of theoretical studies of rotationally resolved photoelectron spectra of the CH, NH, and OH radicals, including predictions of zero-kinetic-energy (ZEKE) spectra for molecular ions produced via resonance enhanced multiphoton ionization. The influence of dynamical features such as Cooper minima, orbital evolution, and 1 mixing are examined for photoionization of the 3σ Rydberg orbital in these radicals. We also make specific predictions for the photoelectron spectra for each molecule within the context of current experimental capabilities.
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| Alternate Title: | Studies of Photoionization Dynamics of CH, NH, and OH Radicals at Near-Threshold | |||||||||
| Additional Information: | © 1994 American Chemical Society. Received: August 5, 1993; In Final Form: October 20, 1993. This work was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the U.S. Department of Energy. We acknowledge the use of resources of the Jet Propulsion Laboratory/California Institute Technology CRAY Y-MP2E/116 Supercomputer | |||||||||
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| Issue or Number: | 2 | |||||||||
| Record Number: | CaltechAUTHORS:20151110-111102505 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151110-111102505 | |||||||||
| Official Citation: | Studies of photoionization dynamics of methylidyne, imidogen, and hydroxyl radicals at near-threshold photoelectron kinetic energies Kwanghsi Wang, J. A. Stephens, and V. McKoy The Journal of Physical Chemistry 1994 98 (2), 460-466 DOI: 10.1021/j100053a019 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 62027 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 10 Nov 2015 21:57 | |||||||||
| Last Modified: | 03 Oct 2019 09:14 |
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