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Studies of photoionization dynamics of methylidyne, imidogen, and hydroxyl radicals at near-threshold photoelectron kinetic energies

Wang, Kwanghsi and Stephens, J. A. and McKoy, V. (1994) Studies of photoionization dynamics of methylidyne, imidogen, and hydroxyl radicals at near-threshold photoelectron kinetic energies. Journal of Physical Chemistry, 98 (2). pp. 460-466. ISSN 0022-3654. https://resolver.caltech.edu/CaltechAUTHORS:20151110-111102505

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Abstract

We discuss results of theoretical studies of rotationally resolved photoelectron spectra of the CH, NH, and OH radicals, including predictions of zero-kinetic-energy (ZEKE) spectra for molecular ions produced via resonance enhanced multiphoton ionization. The influence of dynamical features such as Cooper minima, orbital evolution, and 1 mixing are examined for photoionization of the 3σ Rydberg orbital in these radicals. We also make specific predictions for the photoelectron spectra for each molecule within the context of current experimental capabilities.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/j100053a019DOIArticle
http://pubs.acs.org/doi/abs/10.1021/j100053a019PublisherArticle
Alternate Title:Studies of Photoionization Dynamics of CH, NH, and OH Radicals at Near-Threshold
Additional Information:© 1994 American Chemical Society. Received: August 5, 1993; In Final Form: October 20, 1993. This work was supported by grants from the Air Force Office of Scientific Research and the Office of Health and Environmental Research of the U.S. Department of Energy. We acknowledge the use of resources of the Jet Propulsion Laboratory/California Institute Technology CRAY Y-MP2E/116 Supercomputer
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Funding AgencyGrant Number
Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Department of Energy (DOE)UNSPECIFIED
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Caltech Arthur Amos Noyes Laboratory of Chemical Physics8836
Issue or Number:2
Record Number:CaltechAUTHORS:20151110-111102505
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151110-111102505
Official Citation:Studies of photoionization dynamics of methylidyne, imidogen, and hydroxyl radicals at near-threshold photoelectron kinetic energies Kwanghsi Wang, J. A. Stephens, and V. McKoy The Journal of Physical Chemistry 1994 98 (2), 460-466 DOI: 10.1021/j100053a019
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:62027
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:10 Nov 2015 21:57
Last Modified:03 Oct 2019 09:14

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