Moore, Gordon E. and Badger, Richard M. (1952) The Infrared Spectra and Structure of the Chloramines and Nitrogen Trichloride. Journal of the American Chemical Society, 74 (23). pp. 6076-6080. ISSN 0002-7863. doi:10.1021/ja01143a073. https://resolver.caltech.edu/CaltechAUTHORS:20151110-112449953
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Abstract
The infrared vibration-rotation spectra of gaseous NH_2Cl, NHDCl, NDCl_2 and NCl_3 were investigated from 1.4 to 25µ. Several fundamental vibrations were identified, and the large rotational constants were evaluated for NH_2Cl, NHDCl and NHCl_2. With the assistance of reasonable assumptions regarding other parameters these were used to calculate an H-N-Cl angle of 102° in NH,Cl, and suggest that ∠Cl-N-Cl = 106° and r_(N-CI) = 1.76 Å in NHCl_2. These parameters are interpreted on the basis of simple electronic considerations.
| Item Type: | Article | |||||||||
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| Additional Information: | © 1952 American Chemical Society. Received June 9, 1952. We are indebted to Professor Verner Schomaker for discussions regarding structural considerations. | |||||||||
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| Issue or Number: | 23 | |||||||||
| DOI: | 10.1021/ja01143a073 | |||||||||
| Record Number: | CaltechAUTHORS:20151110-112449953 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20151110-112449953 | |||||||||
| Official Citation: | The Infrared Spectra and Structure of the Chloramines and Nitrogen Trichloride Gordon E. Moore and Richard M. Badger Journal of the American Chemical Society 1952 74 (23), 6076-6080 DOI: 10.1021/ja01143a073 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 62028 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | George Porter | |||||||||
| Deposited On: | 10 Nov 2015 22:07 | |||||||||
| Last Modified: | 10 Nov 2021 22:57 |
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