CaltechAUTHORS
  A Caltech Library Service

The Infrared Spectra and Structure of the Chloramines and Nitrogen Trichloride

Moore, Gordon E. and Badger, Richard M. (1952) The Infrared Spectra and Structure of the Chloramines and Nitrogen Trichloride. Journal of the American Chemical Society, 74 (23). pp. 6076-6080. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20151110-112449953

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20151110-112449953

Abstract

The infrared vibration-rotation spectra of gaseous NH_2Cl, NHDCl, NDCl_2 and NCl_3 were investigated from 1.4 to 25µ. Several fundamental vibrations were identified, and the large rotational constants were evaluated for NH_2Cl, NHDCl and NHCl_2. With the assistance of reasonable assumptions regarding other parameters these were used to calculate an H-N-Cl angle of 102° in NH,Cl, and suggest that ∠Cl-N-Cl = 106° and r_(N-CI) = 1.76 Å in NHCl_2. These parameters are interpreted on the basis of simple electronic considerations.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja01143a073DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja01143a073PublisherArticle
Additional Information:© 1952 American Chemical Society. Received June 9, 1952. We are indebted to Professor Verner Schomaker for discussions regarding structural considerations.
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Gates and Crellin Laboratories of Chemistry1696
Issue or Number:23
Record Number:CaltechAUTHORS:20151110-112449953
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151110-112449953
Official Citation:The Infrared Spectra and Structure of the Chloramines and Nitrogen Trichloride Gordon E. Moore and Richard M. Badger Journal of the American Chemical Society 1952 74 (23), 6076-6080 DOI: 10.1021/ja01143a073
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:62028
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:10 Nov 2015 22:07
Last Modified:03 Oct 2019 09:14

Repository Staff Only: item control page