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The Cation H_(13)O_6+: A Short, Symmetric Hydrogen Bond

Bell, Robert A. and Christoph, Gary G. and Fronczek, Frank R. and Marsh, Richard E. (1975) The Cation H_(13)O_6+: A Short, Symmetric Hydrogen Bond. Science, 190 (4210). pp. 151-152. ISSN 0036-8075. http://resolver.caltech.edu/CaltechAUTHORS:20151116-143721145

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Abstract

The H_(13)O_6+ ion has been found to exist as a discrete entity, forming when the cage compound [(C_9H_(18)_3(NH)_2Cl]+Cl is crystallized from hydrochloric acid solution. The aquo-cation H_(13)O_6 has crystallographic symmetry 2/m (C_(2h)). The central bond O••H••O is symmetric, with a length of 2.39 ± 0.02 angstroms; the four outer hydrogen bonds are asymmetric, with a length of 2.52 ± 0.01 angstroms. The cage compound consists of a chloride ion encapsulated within a triply bridged diammonium species, with hydrogen bond distances N(H)••Cl of 3.10 ± 0.01 angstroms.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1126/science.190.4210.151DOIArticle
http://www.sciencemag.org/content/190/4210/151.extractPublisherArticle
http://www.jstor.org/stable/1740946JSTORArticle
Additional Information:© 1975 American Association for the Advancement of Science. 3 March 1975.
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Arthur Amos Noyes Laboratory of Chemical Physics5066
Record Number:CaltechAUTHORS:20151116-143721145
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20151116-143721145
Official Citation:The Cation H13O6+: A Short, Symmetric Hydrogen Bond Robert A. Bell, Gary G. Christoph, Frank R. Fronczek, and Richard E. Marsh Science 10 October 1975: 190 (4210), 151-152. [DOI:10.1126/science.190.4210.151]
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:62134
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:16 Nov 2015 23:30
Last Modified:13 Feb 2019 18:06

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