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Studies of NiN_2 as a model for photoemission from N_2 adsorbed on nickel

Dubs, Richard L. and McKoy, Vincent (1987) Studies of NiN_2 as a model for photoemission from N_2 adsorbed on nickel. Chemical Physics Letters, 142 (3-4). pp. 237-240. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20151117-122646734

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Abstract

We report a theoretical study of angle-resolved photoelectron spectra (ARPES) for the oriented, linear triatomic NiN_2. This study was motivated by the work of Horn et al. (Surface Sci. 118 (1982) 465 ), who studied ARPES spectra from N2 adsorbed on Ni[110] and observed a resonance feature in the 2σ_u cross section which is not present in the gas phase N_2 spectra. We confirm that this feature could be a result of symmetry breaking of the homonuclear N_2 orbitals by the surface. However, in this case we find that surface reflection of the emitted electrons cannot be ignored in interpretation of the experimental data.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0009-2614(87)80929-6DOIArticle
http://www.sciencedirect.com/science/article/pii/0009261487809296PublisherArticle
Additional Information:© 1987 Elsevier. Received 10 August 1987; in final form 1 October 1987. This work was supported by Grant CHE-8521391 from the National Science Foundation. We also acknowledge use of the resources of the San Diego Supercomputer Center which is supported by the National Science Foundation.
Funders:
Funding AgencyGrant Number
NSFCHE-8521391
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Other Numbering System NameOther Numbering System ID
Caltech Arthur Amos Noyes Laboratory of Chemical Physics7634
Issue or Number:3-4
Record Number:CaltechAUTHORS:20151117-122646734
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20151117-122646734
Official Citation:Richard L.Dubs, Vincent McKoy, Studies of NiN2 as a model for photoemission from N2 adsorbed on nickel, Chemical Physics Letters, Volume 142, Issues 3–4, 11 December 1987, Pages 237-240, ISSN 0009-2614, http://dx.doi.org/10.1016/0009-2614(87)80929-6. (http://www.sciencedirect.com/science/article/pii/0009261487809296)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:62174
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:17 Nov 2015 20:50
Last Modified:03 Oct 2019 09:16

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