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Vibrationally resolved studies of the 2π photoionization of NO

Lynch, D. L. and Schneider, B. I. and Collins, L. A. and McKoy, V. and Huo, W. M. (1988) Vibrationally resolved studies of the 2π photoionization of NO. Chemical Physics Letters, 147 (6). pp. 529-534. ISSN 0009-2614. doi:10.1016/0009-2614(88)80262-8.

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We report the results of studies of the vibrationally resolved photoelectron angular distributions and vibrational branching ratios for 2π photoionization of NO leading to the X ^1Σ^+ state of NO^+. These results were obtained using single-particle frozen-core Hartree-Fock continuum functions for the photoelectron. These studies assess the role of the kσ shape resonance in the 11–18 eV photon energy range where broad non-Franck-Condon structure has been observed. In addition we demonstrate the importance of obtaining both the photoelectron angular distributions as well as the total cross sections in elucidating the relevant resonance features.

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Additional Information:© 1988 Elsevier Science Publishers B.V. Received 31 March 1988. The authors would like to thank S.H. Southworth, A.C. Parr, J.E. Bardis, and J.L. Dehmer for helpful discussions and access to their experimental results prior to publication. Work at the California Institute of Technology was supported by NSF Grant number CHE 85.
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Issue or Number:6
Record Number:CaltechAUTHORS:20151117-122647005
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:62175
Deposited By: Ruth Sustaita
Deposited On:17 Nov 2015 20:46
Last Modified:10 Nov 2021 22:59

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