Augustyn, Katherine E. and Genereux, Joseph C. and Barton, Jacqueline K. (2007) Distance-Independent DNA Charge Transport across an Adenine Tract. Angewandte Chemie International Edition, 46 (30). pp. 5731-5733. ISSN 1433-7851. doi:10.1002/anie.200701522. https://resolver.caltech.edu/CaltechAUTHORS:20160210-145408316
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Abstract
Charging along: DNA-mediated charge transport across adenine tracts is monitored by using a probe interior to the bridge (N^6-cyclopropyladenine (^(CP)A), shown in red). This trap was incorporated serially across the bridge and could be oxidized by a distal rhodium photooxidant without significant attenuation in yield over a distance of 5 nm. These results are consistent with complete delocalization of charge across the DNA bridge.
| Item Type: | Article | ||||||
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| Additional Information: | © 2007 WILEY-VCH Verlag. Received: April 7, 2007 Revised: May 11, 2007. Article first published online: 2 Jul 2007. We are grateful to the NIH (GM49216) for their financial support. We thank M. Davis and F. Shao for expert assistance. | ||||||
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| Subject Keywords: | adenine; charge transfer; DNA; photooxidation | ||||||
| Issue or Number: | 30 | ||||||
| DOI: | 10.1002/anie.200701522 | ||||||
| Record Number: | CaltechAUTHORS:20160210-145408316 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160210-145408316 | ||||||
| Official Citation: | Augustyn, Katherine E., Genereux, Joseph C. and Barton, Jacqueline K. (2007), Distance-Independent DNA Charge Transport across an Adenine Tract. Angew. Chem. Int. Ed., 46: 5731–5733. doi: 10.1002/anie.200701522 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 64385 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Ruth Sustaita | ||||||
| Deposited On: | 10 Feb 2016 23:39 | ||||||
| Last Modified: | 10 Nov 2021 23:30 |
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