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Mechanistic insights into photo-induced, copper-catalyzed alkylations of amines

Ahn, Jun Myun and Hannoun, Kareem and Ratani, Tanvi and Creutz, Sidney and Peters, Jonas C. and Fu, Gregory C. (2015) Mechanistic insights into photo-induced, copper-catalyzed alkylations of amines. In: 45th Western Regional Meeting of the American Chemical Society, 6-8 November 2015, San Marcos, CA.

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Photoinduced, copper-catalyzed cross-couplings have emerged as an attractive class of lightdriven transformations to construct carbon-nitrogen bonds in recent years. Despite the broadening scope with respect to coupling partners, the understanding of the operating mechanisms has been limited to date. Herein, a mechanistic investigation of a photoinduced, copper-catalyzed cross-coupling of amines and alkyl halides, including spectroscopic evidence for a copper intermediate, is presented.

Item Type:Conference or Workshop Item (Paper)
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URLURL TypeDescription Website
Hannoun, Kareem0000-0003-3176-1104
Creutz, Sidney0000-0003-4440-5336
Peters, Jonas C.0000-0002-6610-4414
Fu, Gregory C.0000-0002-0927-680X
Additional Information:© 2015 American Chemical Society.
Record Number:CaltechAUTHORS:20160302-081446965
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:64949
Deposited By: Tony Diaz
Deposited On:02 Mar 2016 17:13
Last Modified:10 Dec 2020 20:54

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