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Metal-catalyzed cross-coupling reactions of alkyl electrophiles

Fu, Gregory C. (2016) Metal-catalyzed cross-coupling reactions of alkyl electrophiles. In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA.

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Despite the tremendous accomplishments that have been described in the development of transition metal- catalyzed coupling processes, it is nevertheless true that many significant opportunities remain. For example, to date the overwhelming majority of studies have focused on couplings between two sp - hybridized reaction sites (e.g., an aryl metal with an aryl halide) . As of 2001, there were relatively few examples of metal- catalyzed coupling reactions of alkyl electrophiles. During the past decade, we have pursued the discovery of transition metal- based catalysts for coupling activated and unactivated alkyl electrophiles that bear β hydrogens. Our recent efforts to develop broadly applicable methods, including enantioselective processes, will be discussed.

Item Type:Conference or Workshop Item (Paper)
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Fu, Gregory C.0000-0002-0927-680X
Additional Information:© 2016 American Chemical Society.
Record Number:CaltechAUTHORS:20160407-124341537
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:65997
Deposited By: Tony Diaz
Deposited On:13 Apr 2016 18:38
Last Modified:03 Oct 2019 09:52

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