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Ethylene and alpha olefin trimerization and tandem trimerization/polymerization of ethylene

Bercaw, John and Do, Loi and Sattler, Aaron and Aluthge, Dinesh and Labinger, Jay and Al Harthi, Mamdouh (2016) Ethylene and alpha olefin trimerization and tandem trimerization/polymerization of ethylene. In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA. http://resolver.caltech.edu/CaltechAUTHORS:20160413-093800561

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Abstract

Mechanistic studies of homogeneous chromium- and titanium- catalyzed trimerization of ethylene will be described. These studies point to a principal pathway for catalyst decompn. for the Fujita titanium system- conproportionation to Ti(III). Accordingly, a silica /MAO supported version has been prepd. and shown to give greater than 10 times higher turnover no. as compared with the homogeneous version under the same conditions. The high activity of the supported Fujita system allows for alpha olefin trimerization to largely two trimers. Tandem and supported- tandem ethylene polymn. and trimerization catalysts yield linear low d. polyethylene from an ethylene-only stock.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
http://www.acs.org/content/acs/en/meetings/spring-2016.htmlOrganizationConference Website
ORCID:
AuthorORCID
Labinger, Jay0000-0002-1942-9232
Additional Information:© 2016 American Chemical Society.
Record Number:CaltechAUTHORS:20160413-093800561
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20160413-093800561
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:66108
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:13 Apr 2016 17:19
Last Modified:19 Sep 2017 17:28

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