Agapie, Theodor (2016) Small molecule activation with metal complexes supported by ligands with pendant arene moieties. In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA. https://resolver.caltech.edu/CaltechAUTHORS:20160413-135238397
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Abstract
Multidentate ligands connected by terphenyl linkers have been employed to support mono and multimetallic complexes. The central arene of the terphenyl unit acts as a labile donor and coordinates in a variety of modes as a function of metal and oxidn. state. This arene can be non- innocent with respect to redox and H-transfer chem. Variants with catechol and hydroquinone moieties show multi- proton, multi- electron transfer chem. Addnl., pendant phosphine arms can reversibly dissoc., facilitating reactivity. The reactivity of these complexes for the activation of small mols. such as H_2, N_2, CO_2, O_2, and CO will be discussed.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2016 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20160413-135238397 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160413-135238397 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 66128 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 13 Apr 2016 20:56 | ||||||
| Last Modified: | 03 Oct 2019 09:53 |
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