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Evolution of alpha-pinene oxidation products in the presence of varying oxidizers: CI-APi-TOF point of view

Rissanen, Matti P. and Jokinen, Tuija and Schobesberger, Siegfried and Praplan, Arnaud P. and Sipilä, Mikko and Sarnela, Nina and Junninen, Heikki and Duplissy, Jonathan and Kangasluoma, Juha and Hakala, Jani and Wimmer, Daniela and Adamov, Alexey and Lehtipalo, Katrianne and Nieminen, Tuomo and Kulmala, Markku and Worsnop, Douglas R. (2013) Evolution of alpha-pinene oxidation products in the presence of varying oxidizers: CI-APi-TOF point of view. In: Nucleation and Atmospheric Aerosols. AIP Conference Proceedings. No.1527. American Institute of Physics , Melville, NY, pp. 371-373. ISBN 978-0-7354-1152-4.

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Alpha-pinene oxidation was studied in the CERN CLOUD chamber under near atmospheric conditions using varying levels of different oxidizers (i.e., O_3 , HO_x and NO_x with differing gas mixture compositions) in the presence and absence of UV-radiation, SO_2 and additional organic traces; ammonia (NH_3) and dimethylamine (DMA). The oxidation products and their evolution due to aging in the chamber were studied using a novel CI-APi-TOF technique, with the nitrate ion (NO^−_3 ) based chemical ionization (CI) scheme. We aimed to the results that would indicate how different oxidizing pathways lead to different product distributions in the product clusters detected.

Item Type:Book Section
Related URLs:
URLURL TypeDescription
Rissanen, Matti P.0000-0003-0463-8098
Worsnop, Douglas R.0000-0002-8928-8017
Additional Information:© 2013 AIP Publishing LLC. Published online 24 May 2013. We would like to thank CERN for supporting CLOUD with important technical and financial resources, and for providing a particle beam from the CERN Proton Synchrotron. This research has received funding from the EC Seventh Framework Programme (Marie Curie Initial Training Network "CLOUD-ITN" no. 215072, MCITN "CLOUD-TRAIN" no. 316662, and ERC-Advanced "ATMNUCLE'' grant no. 227463), the German Federal Ministry of Education and Research (project nos. 01LK0902A and 01LK1222A), the Swiss National Science Foundation (project nos. 200020_135307 and 206620_130527), the Academy of Finland (Center of Excellence project no. 1118615), the Academy of Finland (135054, 133872, 251427, 139656, 139995, 137749, 141217, 141451), the Finnish Funding Agency for Technology and Innovation, the Nessling Foundation, the Austrian Science Fund (FWF; project no. P19546 and L593), the Portuguese Foundation for Science and Technology (project no. CERN/FP/116387/2010), the Swedish Research Council, Vetenskapsrådet (grant 2011-5120), the Presidium of the Russian Academy of Sciences and Russian Foundation for Basic Research (grants 08-02-91006-CERN and 12-02-91522-CERN), and the U.S. National Science Foundation (grants AGS1136479 and CHE1012293).
Funding AgencyGrant Number
Marie Curie Fellowship215072
Marie Curie Fellowship316662
European Research Council (ERC)227463
Bundesministerium für Bildung und Forschung (BMBF)01LK0902A
Bundesministerium für Bildung und Forschung (BMBF)01LK1222A
Swiss National Science Foundation (SNSF)200020_135307
Swiss National Science Foundation (SNSF)206620_130527
Academyof Finland1118615
Academy of Finland135054
Academy of Finland133872
Academy of Finland251427
Academy of Finland139656
Academy of Finland139995
Academy of Finland137749
Academy of Finland141217
Academy of Finland141451
Finnish Funding Agency for Technology and InnovationUNSPECIFIED
Nessling FoundationUNSPECIFIED
FWF Der WissenschaftsfondsP19546
FWF Der WissenschaftsfondsL593
Fundação para a Ciência e a Tecnologia (FCT)CERN/FP/116387/2010
Russian Foundation for Basic Research08-02-91006-CERN
Russian Foundation for Basic Research12-02-91522-CERN
Swedish Research CouncilUNSPECIFIED
Russian Academy of SciencesUNSPECIFIED
Subject Keywords:Chemical ionization mass spectrometer, alfa-pinene oxidation, oxidized organics
Series Name:AIP Conference Proceedings
Issue or Number:1527
Classification Code:PACS: 92.60.Mt
Record Number:CaltechAUTHORS:20160421-142028781
Persistent URL:
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:66373
Deposited By: Ruth Sustaita
Deposited On:22 Apr 2016 01:02
Last Modified:10 Nov 2021 23:57

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