Del Ciello, Sarah A. and Winkler, Jay R. and Peters, Jonas C. and Gray, Harry B. (2016) Mechanistic investigation of proton reduction by cobaloximes: Insight from H2 oxidation kinetics. In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA. https://resolver.caltech.edu/CaltechAUTHORS:20160504-105818808
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Abstract
Cobaloximes are a class of earth- abundant proton redn. catalysts that have been known since the 1980's. Previous studies have come to conflicting conclusions about the mechanism of proton redn. by these catalysts, with evidence existing for both a homolytic and heterolytic mechanism. In this work, kinetic anal. of the reverse reaction is used to gain further insight.
| Item Type: | Conference or Workshop Item (Paper) | ||||||||
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| Additional Information: | © 2016 American Chemical Society. | ||||||||
| Group: | CCI Solar Fuels | ||||||||
| Record Number: | CaltechAUTHORS:20160504-105818808 | ||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160504-105818808 | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 66650 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | Tony Diaz | ||||||||
| Deposited On: | 04 May 2016 19:54 | ||||||||
| Last Modified: | 22 Nov 2019 09:58 |
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