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Mechanistic investigation of proton reduction by cobaloximes: Insight from H2 oxidation kinetics

Del Ciello, Sarah A. and Winkler, Jay R. and Peters, Jonas C. and Gray, Harry B. (2016) Mechanistic investigation of proton reduction by cobaloximes: Insight from H2 oxidation kinetics. In: 251st American Chemical Society National Meeting & Exposition, March 13-17, 2016, San Diego, CA. http://resolver.caltech.edu/CaltechAUTHORS:20160504-105818808

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Abstract

Cobaloximes are a class of earth- abundant proton redn. catalysts that have been known since the 1980's. Previous studies have come to conflicting conclusions about the mechanism of proton redn. by these catalysts, with evidence existing for both a homolytic and heterolytic mechanism. In this work, kinetic anal. of the reverse reaction is used to gain further insight.


Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription
http://www.acs.org/content/acs/en/meetings/spring-2016.htmlOrganizationConference Website
ORCID:
AuthorORCID
Winkler, Jay R.0000-0002-4453-9716
Peters, Jonas C.0000-0002-6610-4414
Additional Information:© 2016 American Chemical Society.
Group:CCI Solar Fuels
Record Number:CaltechAUTHORS:20160504-105818808
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20160504-105818808
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:66650
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:04 May 2016 19:54
Last Modified:15 Sep 2017 18:25

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