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Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst

Ren, Limin and Guo, Qiang and Orazov, Marat and Xu, Dandan and Politi, Dorothea and Kumar, Prashant and Alhassan, Saeed M. and Mkhoyan, K. Andre and Sidiras, Dimitrios and Davis, Mark E. and Tsapatsis, Michael (2016) Pillared Sn-MWW Prepared by a Solid-State-Exchange Method and its Use as a Lewis Acid Catalyst. ChemCatChem, 8 (7). pp. 1274-1278. ISSN 1867-3880. doi:10.1002/cctc.201600120.

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Pillared Sn-MWW (Sn-MWW(SP)-SSE) was prepared through a solid-state-exchange (SSE) route. The pillared structure was inherited from pillared B-MWW, and Sn was inserted in the framework by boron leaching and solid-state-exchange with tin tetrachloride pentahydrate. The Sn-MWW(SP)-SSE with framework Sn sites exhibits Lewis acidity and good catalytic performance for the Baeyer–Villiger oxidation, and mono- and disaccharide isomerizations.

Item Type:Article
Related URLs:
URLURL TypeDescription
Xu, Dandan0000-0002-0355-2906
Davis, Mark E.0000-0001-8294-1477
Tsapatsis, Michael0000-0001-5610-3525
Additional Information:© 2016 John Wiley & Sons, Inc. Manuscript Received: 30 January 2016. First published: 23 March 2016. Funded by U.S. Department of Energy. Grant Number: DE-SC0001004
Funding AgencyGrant Number
Department of Energy (DOE)DE-SC0001004
Subject Keywords:isomerization; layered materials; Lewis acids; solid-state-exchange; zeolites
Issue or Number:7
Record Number:CaltechAUTHORS:20160512-084540662
Persistent URL:
Official Citation:L. Ren, Q. Guo, M. Orazov, D. Xu, D. Politi, P. Kumar, S. M. Alhassan, K. A. Mkhoyan, D. Sidiras, M. E. Davis, M. Tsapatsis, ChemCatChem 2016, 8, 1274.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:67040
Deposited By: Tony Diaz
Deposited On:12 May 2016 23:39
Last Modified:11 Nov 2021 00:26

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