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Synthesis and direct spectroscopic observation of N-(2,2,5,5-tetramethylpyrrolidinyl)nitrene. Comparison of five- and six-membered cyclic 1,1-dialkyldiazenes

Schultz, Peter G. and Dervan, Peter B. (1980) Synthesis and direct spectroscopic observation of N-(2,2,5,5-tetramethylpyrrolidinyl)nitrene. Comparison of five- and six-membered cyclic 1,1-dialkyldiazenes. Journal of the American Chemical Society, 102 (2). pp. 878-880. ISSN 0002-7863. doi:10.1021/ja00522a090. https://resolver.caltech.edu/CaltechAUTHORS:20160516-092521832

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Abstract

We report the synthesis, infrared and electronic spectra, and the kinetics of the thermal decomposition of N-(2,2,5,5-tetramethylpyrrolidyl)nitrene (1). Because the six-membered ring 1,1-diazene 2 has been characterized, these results allow some estimate of the importance of structure on the spectral properties and kinetic behavior of 1,1-dialkyldiazenes. In addition, the first approximate heat of formation of a 1,1-diazene from experiment is provided.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja00522a090DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00522a090PublisherArticle
ORCID:
AuthorORCID
Dervan, Peter B.0000-0001-8852-7306
Additional Information:© 1980 American Chemical Society. Received August 13, 1979. Publication Date: January 1980. The authors are grateful to the National Science Foundation (CHE75-06776) and the donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research.
Funders:
Funding AgencyGrant Number
NSFCHE75-06776
American Chemical Society Petroleum Research FundUNSPECIFIED
Other Numbering System:
Other Numbering System NameOther Numbering System ID
Caltech Crellin Laboratory of Chemistry6065
Issue or Number:2
DOI:10.1021/ja00522a090
Record Number:CaltechAUTHORS:20160516-092521832
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160516-092521832
Official Citation:Synthesis and direct spectroscopic observation of N-(2,2,5,5-tetramethylpyrrolidinyl)nitrene. Comparison of five- and six-membered cyclic 1,1-dialkyldiazenes Peter G. Schultz and Peter B. Dervan Journal of the American Chemical Society 1980 102 (2), 878-880 DOI: 10.1021/ja00522a090
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:67102
Collection:CaltechAUTHORS
Deposited By: Victoria Brennan
Deposited On:16 May 2016 21:17
Last Modified:11 Nov 2021 00:27

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