Schultz, Peter G. and Dervan, Peter B. (1980) Synthesis and direct spectroscopic observation of N-(2,2,5,5-tetramethylpyrrolidinyl)nitrene. Comparison of five- and six-membered cyclic 1,1-dialkyldiazenes. Journal of the American Chemical Society, 102 (2). pp. 878-880. ISSN 0002-7863. doi:10.1021/ja00522a090. https://resolver.caltech.edu/CaltechAUTHORS:20160516-092521832
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Abstract
We report the synthesis, infrared and electronic spectra, and the kinetics of the thermal decomposition of N-(2,2,5,5-tetramethylpyrrolidyl)nitrene (1). Because the six-membered ring 1,1-diazene 2 has been characterized, these results allow some estimate of the importance of structure on the spectral properties and kinetic behavior of 1,1-dialkyldiazenes. In addition, the first approximate heat of formation of a 1,1-diazene from experiment is provided.
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| Additional Information: | © 1980 American Chemical Society. Received August 13, 1979. Publication Date: January 1980. The authors are grateful to the National Science Foundation (CHE75-06776) and the donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research. | |||||||||
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| Issue or Number: | 2 | |||||||||
| DOI: | 10.1021/ja00522a090 | |||||||||
| Record Number: | CaltechAUTHORS:20160516-092521832 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160516-092521832 | |||||||||
| Official Citation: | Synthesis and direct spectroscopic observation of N-(2,2,5,5-tetramethylpyrrolidinyl)nitrene. Comparison of five- and six-membered cyclic 1,1-dialkyldiazenes Peter G. Schultz and Peter B. Dervan Journal of the American Chemical Society 1980 102 (2), 878-880 DOI: 10.1021/ja00522a090 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 67102 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Victoria Brennan | |||||||||
| Deposited On: | 16 May 2016 21:17 | |||||||||
| Last Modified: | 11 Nov 2021 00:27 |
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