Hinsberg, William D., III and Dervan, Peter B. (1978) Synthesis and direct spectroscopic observation of a 1,1-dialkyldiazene. Infrared and electronic spectrum of N-(2,2,6,6-tetramethylpiperidyl)nitrene. Journal of the American Chemical Society, 100 (5). pp. 1608-1610. ISSN 0002-7863. doi:10.1021/ja00473a051. https://resolver.caltech.edu/CaltechAUTHORS:20160516-094147419
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Abstract
We report here the synthesis and direct observation of a 1, 1-dialkyldiazene, N-(2,2,6,6-tetramethylpiperidyl)nitrene (3). The visible spectrum provides the first experimental information concerning the electronic structure of a 1, 1-dialkyldiazene. Moreover, the infrared spectrum provides evidence that there is considerable double bond character in the N=N bond, similar to a 1,2-diazene (2).
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| Additional Information: | © 1978 American Chemical Society. Publication Date: March 1978. Received September 14, 1977. The authors are grateful to the National Science Foundation (CHE75-06776) and the donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research. We thank W. A. Goddard and J. H. Davis for their interest and helpful discussions during this work. | |||||||||
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| Issue or Number: | 5 | |||||||||
| DOI: | 10.1021/ja00473a051 | |||||||||
| Record Number: | CaltechAUTHORS:20160516-094147419 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160516-094147419 | |||||||||
| Official Citation: | Synthesis and direct spectroscopic observation of a 1,1-dialkyldiazene. Infrared and electronic spectrum of N-(2,2,6,6-tetramethylpiperidyl)nitrene William D. Hinsberg III and Peter B Dervan Journal of the American Chemical Society 1978 100 (5), 1608-1610 DOI: 10.1021/ja00473a051 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 67110 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Victoria Brennan | |||||||||
| Deposited On: | 16 May 2016 21:39 | |||||||||
| Last Modified: | 11 Nov 2021 00:27 |
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