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Synthesis and direct spectroscopic observation of a 1,1-dialkyldiazene. Infrared and electronic spectrum of N-(2,2,6,6-tetramethylpiperidyl)nitrene

Hinsberg, William D., III and Dervan, Peter B. (1978) Synthesis and direct spectroscopic observation of a 1,1-dialkyldiazene. Infrared and electronic spectrum of N-(2,2,6,6-tetramethylpiperidyl)nitrene. Journal of the American Chemical Society, 100 (5). pp. 1608-1610. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20160516-094147419

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Abstract

We report here the synthesis and direct observation of a 1, 1-dialkyldiazene, N-(2,2,6,6-tetramethylpiperidyl)nitrene (3). The visible spectrum provides the first experimental information concerning the electronic structure of a 1, 1-dialkyldiazene. Moreover, the infrared spectrum provides evidence that there is considerable double bond character in the N=N bond, similar to a 1,2-diazene (2).


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja00473a051DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00473a051PublisherArticle
ORCID:
AuthorORCID
Dervan, Peter B.0000-0001-8852-7306
Additional Information:© 1978 American Chemical Society. Publication Date: March 1978. Received September 14, 1977. The authors are grateful to the National Science Foundation (CHE75-06776) and the donors of the Petroleum Research Fund, administered by the American Chemical Society, for support of this research. We thank W. A. Goddard and J. H. Davis for their interest and helpful discussions during this work.
Funders:
Funding AgencyGrant Number
NSFCHE75-06776
American Chemical Society Petroleum Research FundUNSPECIFIED
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Other Numbering System NameOther Numbering System ID
Caltech Crellin Laboratory of Chemistry5664
Issue or Number:5
Record Number:CaltechAUTHORS:20160516-094147419
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160516-094147419
Official Citation:Synthesis and direct spectroscopic observation of a 1,1-dialkyldiazene. Infrared and electronic spectrum of N-(2,2,6,6-tetramethylpiperidyl)nitrene William D. Hinsberg III and Peter B Dervan Journal of the American Chemical Society 1978 100 (5), 1608-1610 DOI: 10.1021/ja00473a051
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:67110
Collection:CaltechAUTHORS
Deposited By: Victoria Brennan
Deposited On:16 May 2016 21:39
Last Modified:03 Oct 2019 10:03

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