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Six-membered cyclic diacyl peroxide fragmentations. Thermal decomposition of meso- and dl-2,3-dimethylsuccinoyl peroxides

Jones, Carol R. and Dervan, Peter B. (1977) Six-membered cyclic diacyl peroxide fragmentations. Thermal decomposition of meso- and dl-2,3-dimethylsuccinoyl peroxides. Journal of the American Chemical Society, 99 (20). pp. 6772-6774. ISSN 0002-7863. http://resolver.caltech.edu/CaltechAUTHORS:20160516-094425023

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Abstract

We report the syntheses and thermal decomposition of meso- and dl-2,3-dimethylsuccinoyl peroxides (1 and 2, respectively). These initial findings provide the first stereochemical study of six-membered cyclic diacyl peroxide thermal fragmentations. The data presented here are consistent with a common intermediate(s) but do not require the generation of electronically excited states of the 2-butene products.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/ja00462a058DOIArticle
http://pubs.acs.org/doi/abs/10.1021/ja00462a058PublisherArticle
ORCID:
AuthorORCID
Dervan, Peter B.0000-0001-8852-7306
Additional Information:© 1977 American Chemical Society. Publication Date: September 1977. Received May 19, 1977. We are grateful to the National Science Foundation (CHE75-06776) and the National Institutes of Health for generous financial support.
Funders:
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NSFCHE75-06776
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Caltech Crellin Laboratory of Chemistry5588
Record Number:CaltechAUTHORS:20160516-094425023
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20160516-094425023
Official Citation:Six-membered cyclic diacyl peroxide fragmentations. Thermal decomposition of meso- and dl-2,3-dimethylsuccinoyl peroxides Carol R. Jones and Peter B. Dervan Journal of the American Chemical Society 1977 99 (20), 6772-6774 DOI: 10.1021/ja00462a058
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:67112
Collection:CaltechAUTHORS
Deposited By: Victoria Brennan
Deposited On:16 May 2016 21:55
Last Modified:09 Nov 2017 00:07

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