Jones, Carol R. and Dervan, Peter B. (1977) Six-membered cyclic diacyl peroxide fragmentations. Thermal decomposition of meso- and dl-2,3-dimethylsuccinoyl peroxides. Journal of the American Chemical Society, 99 (20). pp. 6772-6774. ISSN 0002-7863. doi:10.1021/ja00462a058. https://resolver.caltech.edu/CaltechAUTHORS:20160516-094425023
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Abstract
We report the syntheses and thermal decomposition of meso- and dl-2,3-dimethylsuccinoyl peroxides (1 and 2, respectively). These initial findings provide the first stereochemical study of six-membered cyclic diacyl peroxide thermal fragmentations. The data presented here are consistent with a common intermediate(s) but do not require the generation of electronically excited states of the 2-butene products.
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| Additional Information: | © 1977 American Chemical Society. Publication Date: September 1977. Received May 19, 1977. We are grateful to the National Science Foundation (CHE75-06776) and the National Institutes of Health for generous financial support. | |||||||||
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| Issue or Number: | 20 | |||||||||
| DOI: | 10.1021/ja00462a058 | |||||||||
| Record Number: | CaltechAUTHORS:20160516-094425023 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160516-094425023 | |||||||||
| Official Citation: | Six-membered cyclic diacyl peroxide fragmentations. Thermal decomposition of meso- and dl-2,3-dimethylsuccinoyl peroxides Carol R. Jones and Peter B. Dervan Journal of the American Chemical Society 1977 99 (20), 6772-6774 DOI: 10.1021/ja00462a058 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 67112 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Victoria Brennan | |||||||||
| Deposited On: | 16 May 2016 21:55 | |||||||||
| Last Modified: | 11 Nov 2021 00:27 |
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