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Trimethylsilyl anions. Direct synthesis of trimethylsilylbenzenes

Shippey, Michael A. and Dervan, Peter B. (1977) Trimethylsilyl anions. Direct synthesis of trimethylsilylbenzenes. Journal of Organic Chemistry, 42 (15). pp. 2654-2655. ISSN 0022-3263. doi:10.1021/jo00435a037.

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The reaction of aryl halides with hexamethyldisilane and potassium methoxide (or sodium methoxide or methyllithium) in hexamethylphosphoric triamide (HMPT) affords the corresponding trimethylsilyl-substituted benzene and some reduction product.

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Dervan, Peter B.0000-0001-8852-7306
Additional Information:© 1977 American Chemical Society. Received March 25, 1977. The authors are grateful to the National Science Foundation (MPS 75-06776) for their generous support of this work. We appreciate stimulating discussions with Professor David A. Evans.
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NFSMPS 75-06776
Issue or Number:15
Record Number:CaltechAUTHORS:20160516-095111703
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Official Citation:Trimethylsilyl anions: direct synthesis of trimethylsilylbenzenes Michael A. Shippey and Peter B. Dervan The Journal of Organic Chemistry 1977 42 (15), 2654-2655 DOI: 10.1021/jo00435a037
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:67113
Deposited By: Victoria Brennan
Deposited On:16 May 2016 20:42
Last Modified:11 Nov 2021 00:27

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