Shippey, Michael A. and Dervan, Peter B. (1977) Trimethylsilyl anions. Direct synthesis of trimethylsilylbenzenes. Journal of Organic Chemistry, 42 (15). pp. 2654-2655. ISSN 0022-3263. doi:10.1021/jo00435a037. https://resolver.caltech.edu/CaltechAUTHORS:20160516-095111703
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Abstract
The reaction of aryl halides with hexamethyldisilane and potassium methoxide (or sodium methoxide or methyllithium) in hexamethylphosphoric triamide (HMPT) affords the corresponding trimethylsilyl-substituted benzene and some reduction product.
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| Additional Information: | © 1977 American Chemical Society. Received March 25, 1977. The authors are grateful to the National Science Foundation (MPS 75-06776) for their generous support of this work. We appreciate stimulating discussions with Professor David A. Evans. | |||||||||
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| Issue or Number: | 15 | |||||||||
| DOI: | 10.1021/jo00435a037 | |||||||||
| Record Number: | CaltechAUTHORS:20160516-095111703 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160516-095111703 | |||||||||
| Official Citation: | Trimethylsilyl anions: direct synthesis of trimethylsilylbenzenes Michael A. Shippey and Peter B. Dervan The Journal of Organic Chemistry 1977 42 (15), 2654-2655 DOI: 10.1021/jo00435a037 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 67113 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Victoria Brennan | |||||||||
| Deposited On: | 16 May 2016 20:42 | |||||||||
| Last Modified: | 11 Nov 2021 00:27 |
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