Berson, Jerome A. and Dervan, Peter B. and Jenkins, Jerry A. (1972) Stereospecific double rearrangement of trans-3,4-dimethyl-cis,trans-cycloocta-1,5-diene to cis-3,4-dimethyl-cis,cis-cycloocta-1,5-diene. Journal of the American Chemical Society, 94 (21). pp. 7598-7599. ISSN 0002-7863. doi:10.1021/ja00776a065. https://resolver.caltech.edu/CaltechAUTHORS:20160516-100848967
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20160516-100848967
Abstract
The chemistry of the highly strained cis,trans-cyclo-octa- 1,5-diene ring system* (1) is largely unexplored. Because there is a possibility that the corresponding 3,4-dimethyl derivatives 2 and 3 may be involved in the thermal nonboat, “crossover” rearrangement of cis- 1,2-cis,trans- and cis- 1,2-cis,cis-dipropenylcyclobutanes (cCT and cCC, respectively),3 we have carried out a study of the pyrolysis of trans-3,4-dimethyl-cis,trans- cyclo-octa- 1,5-diene (3). The present paper reports a new thermal rearrangement of this compound.
| Item Type: | Article | |||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| |||||||||
| ORCID: |
| |||||||||
| Additional Information: | © 1972 American Chemical Society. Received August 5, 1972. We thank the National Science Foundation (Grant No. GP-33909X) and the Hofmann-La Roche Foundation for partial support of this work. | |||||||||
| Funders: |
| |||||||||
| Issue or Number: | 21 | |||||||||
| DOI: | 10.1021/ja00776a065 | |||||||||
| Record Number: | CaltechAUTHORS:20160516-100848967 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160516-100848967 | |||||||||
| Official Citation: | Stereospecific double rearrangement of trans-3,4-dimethyl-cis,trans-cycloocta-1,5-diene to cis-3,4-dimethyl-cis,cis-cycloocta-1,5-diene Jerome A. Berson, Peter B. Dervan, and Jerry A. Jenkins Journal of the American Chemical Society 1972 94 (21), 7598-7599 DOI: 10.1021/ja00776a065 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 67123 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Victoria Brennan | |||||||||
| Deposited On: | 16 May 2016 22:00 | |||||||||
| Last Modified: | 11 Nov 2021 00:27 |
Repository Staff Only: item control page
