Murialdo, Maxwell and Stadie, Nicholas P. and Ahn, Channing C. and Fultz, B. (2016) A Generalized Law of Corresponding States for the Physisorption of Classical Gases with Cooperative Adsorbate-Adsorbate Interactions. Journal of Physical Chemistry C, 120 (22). pp. 11847-11853. ISSN 1932-7447. doi:10.1021/acs.jpcc.6b00289. https://resolver.caltech.edu/CaltechAUTHORS:20160524-080846455
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Abstract
The Law of Corresponding States for classical gases is well established. Recent attempts at developing an analogous Law of Corresponding States for gas physisorption, however, have had limited success, in part due to the omission of relevant adsorption considerations such as the adsorbate volume and cooperative adsorbate-adsorbate interactions. In this work, we modify a prior Law of Corresponding States for gas physisorption to account for adsorbate volume, and test it with experimental data and a generalized theoretical approach. Furthermore, we account for the recently-reported cooperative adsorbate-adsorbate interactions on the surface of zeolite-templated carbon (ZTC) with an Ising-type model, and in doing so, show that the Law of Corresponding States for gas physisorption remains valid even in the presence of atypically enhanced adsorbate-adsorbate interactions.
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| Additional Information: | © 2016 American Chemical Society. Received: January 11, 2016; Revised: May 10, 2016; Published: May 12, 2016. This work was sponsored as a part of EFree (Energy Frontier Research in Extreme Environments), an Energy Frontier Research Center funded by the US Department of Energy, Office of Science, Basic Energy Sciences under Award Number DESC0001057. | |||||||||
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| Issue or Number: | 22 | |||||||||
| DOI: | 10.1021/acs.jpcc.6b00289 | |||||||||
| Record Number: | CaltechAUTHORS:20160524-080846455 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160524-080846455 | |||||||||
| Official Citation: | A Generalized Law of Corresponding States for the Physisorption of Classical Gases with Cooperative Adsorbate–Adsorbate Interactions Maxwell Murialdo, Nicholas P. Stadie, Channing C. Ahn, and Brent Fultz The Journal of Physical Chemistry C 2016 120 (22), 11847-11853 DOI: 10.1021/acs.jpcc.6b00289 | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 67284 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Tony Diaz | |||||||||
| Deposited On: | 24 May 2016 18:34 | |||||||||
| Last Modified: | 11 Nov 2021 00:30 |
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