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Quantification of ATOFMS Data by Multivariate Methods

Fergenson, David P. and Song, Xin-Hua and Ramadan, Ziad and Allen, Jonathan O. and Hughes, Lara S. and Cass, Glen R. and Hopke, Philip K. and Prather, Kimberly A. (2001) Quantification of ATOFMS Data by Multivariate Methods. Analytical Chemistry, 73 (15). pp. 3535-3541. ISSN 0003-2700. https://resolver.caltech.edu/CaltechAUTHORS:20160607-145728212

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Abstract

Aerosol time-of-flight mass spectrometry (ATOFMS) is capable of measuring the sizes and chemical compositions of individual polydisperse aerosol particles in real time. A qualitative estimate of the particle composition is acquired in the form of a mass spectrum that must be subsequently interpreted in order to draw conclusions regarding atmospheric relevance. The actual problem involves developing a calibration that allows the mass spectral data to be transformed into estimates of the composition of the atmospheric aerosol. A properly calibrated ATOFMS system should be able to quantitatively determine atmospheric concentrations of various species. Ideally, it would be able to accomplish this more rapidly, accurately, with higher size and time resolution, and at a far lower marginal cost than the manual sampling methods that are currently employed. Attempts have already been made at using ATOFMS and similar techniques to extract the bulk chemical species concentration present in an ensemble of particles. This study represents the use of a multivariate calibration method, two-dimensional partial least-squares analysis, for calibrating single-particle mass spectral data. The method presented here is far less labor-intensive than the univariate methods attempted to date and allows for less observer bias. Because of the labor savings, this is also the most comprehensive calibration performed to date, resulting in the quantification of 44 different chemical species.


Item Type:Article
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URLURL TypeDescription
http://dx.doi.org/10.1021/ac010022jDOIArticle
http://pubs.acs.org/doi/abs/10.1021/ac010022jPublisherArticle
Additional Information:© 2001 American Chemical Society. Received for review January 5, 2001. Accepted May 18, 2001. This work was supported in part by the State of California Air Resources Board through Contract 97-321.
Funders:
Funding AgencyGrant Number
California Air Resources Board97-321
Issue or Number:15
Record Number:CaltechAUTHORS:20160607-145728212
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160607-145728212
Official Citation:Quantification of ATOFMS Data by Multivariate Methods David P. Fergenson, Xin-Hua Song, Ziad Ramadan, Jonathan O. Allen, Lara S. Hughes, Glen R. Cass, Philip K. Hopke,and Kimberly A. Prather Analytical Chemistry 2001 73 (15), 3535-3541 DOI: 10.1021/ac010022j
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:67753
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:08 Jun 2016 17:28
Last Modified:03 Oct 2019 10:08

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