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Shock synthesis of quasicrystals with implications for their origin in asteroid collisions

Asimow, Paul D. and Lin, Chaney and Bindi, Luca and Ma, Chi and Tschauner, Oliver and Hollister, Lincoln S. and Steinhardt, Paul J. (2016) Shock synthesis of quasicrystals with implications for their origin in asteroid collisions. Proceedings of the National Academy of Sciences of the United States of America, 113 (26). pp. 7077-7081. ISSN 0027-8424. PMCID PMC4932946. https://resolver.caltech.edu/CaltechAUTHORS:20160613-121621550

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Abstract

We designed a plate impact shock recovery experiment to simulate the starting materials and shock conditions associated with the only known natural quasicrystals, in the Khatyrka meteorite. At the boundaries among CuAl_5, (Mg_(0.75)Fe^(2+)_(0.25))_2SiO_4 olivine, and the stainless steel chamber walls, the recovered specimen contains numerous micron-scale grains of a quasicrystalline phase displaying face-centered icosahedral symmetry and low phason strain. The compositional range of the icosahedral phase is Al_(68–73)Fe_(11–16)Cu_(10–12)Cr_(1–4)Ni_(1–2) and extends toward higher Al/(Cu+Fe) and Fe/Cu ratios than those reported for natural icosahedrite or for any previously known synthetic quasicrystal in the Al-Cu-Fe system. The shock-induced synthesis demonstrated in this experiment reinforces the evidence that natural quasicrystals formed during a shock event but leaves open the question of whether this synthesis pathway is attributable to the expanded thermodynamic stability range of the quasicrystalline phase at high pressure, to a favorable kinetic pathway that exists under shock conditions, or to both thermodynamic and kinetic factors.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1073/pnas.1600321113DOIArticle
http://www.pnas.org/content/113/26/7077PublisherArticle
http://www.pnas.org/lookup/suppl/doi:10.1073/pnas.1600321113/-/DCSupplementalPublisherSupporting Information
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC4932946/PubMed CentralArticle
ORCID:
AuthorORCID
Asimow, Paul D.0000-0001-6025-8925
Additional Information:© 2016 National Academy of Sciences. Edited by Mark H. Thiemens, University of California, San Diego, La Jolla, CA, and approved May 6, 2016 (received for review January 7, 2016) P.D.A. is supported by US National Science Foundation (NSF) Award EAR-1426526. L.B. is funded with the “60%2013” research funds from the University of Firenze, Italy. C.L. and P.J.S. are supported, in part, by NSF-MRSEC Program Grants DMR-0820341 through New York University and DMR-0819860 through the Princeton Center for Complex Materials. SEM, EDS, EBSD, and EPMA analyses were carried out at the Caltech GPS Division Analytical Facility, which is supported, in part, by NSF Grants EAR-0318518 and DMR-0080065. Author contributions: P.D.A. and P.J.S. designed research; P.D.A., C.L., L.B., C.M., and O.T. performed research; P.D.A., C.L., L.B., C.M., O.T., and L.S.H. analyzed data; and P.D.A., L.B., and P.J.S. wrote the paper. The authors declare no conflict of interest. This article is a PNAS Direct Submission. Data deposition: Crystallographic data on quasicrystals is available from the authors upon request. This article contains supporting information online at www.pnas.org/lookup/suppl/doi:10.1073/pnas.1600321113/-/DCSupplemental.
Funders:
Funding AgencyGrant Number
NSFEAR-1426526
University of Firenze60%2013
NSFDMR-0820341
NSFDMR-0819860
NSFEAR-0318518
NSFDMR-0080065
Subject Keywords:icosahedrite | shock metamorphism | alloys | meteorites | quasicrystals
Issue or Number:26
PubMed Central ID:PMC4932946
Record Number:CaltechAUTHORS:20160613-121621550
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160613-121621550
Official Citation:Paul D. Asimow, Chaney Lin, Luca Bindi, Chi Ma, Oliver Tschauner, Lincoln S. Hollister, and Paul J. Steinhardt Shock synthesis of quasicrystals with implications for their origin in asteroid collisions PNAS 2016 113 (26) 7077-7081; published ahead of print June 13, 2016, doi:10.1073/pnas.1600321113
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:67876
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:13 Jun 2016 19:25
Last Modified:03 Oct 2019 10:09

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