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Secondary Organic Aerosol Formation from Cyclohexene Ozonolysis: Effect of OH Scavenger and the Role of Radical Chemistry

Keywood, M. D. and Kroll, J. H. and Varutbangkul, V. and Bahreini, R. and Flagan, R. C. and Seinfeld, J. H. (2004) Secondary Organic Aerosol Formation from Cyclohexene Ozonolysis: Effect of OH Scavenger and the Role of Radical Chemistry. Environmental Science and Technology, 38 (12). pp. 3343-3350. ISSN 0013-936X. https://resolver.caltech.edu/CaltechAUTHORS:20160614-162310887

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Abstract

To isolate secondary organic aerosol (SOA) formation in ozone-alkene systems from the additional influence of hydroxyl (OH) radicals formed in the gas-phase ozone-alkene reaction, OH scavengers are employed. The detailed chemistry associated with three different scavengers (cyclohexane, 2-butanol, and CO) is studied in relation to the effects of the scavengers on observed SOA yields in the ozone-cyclohexene system. Our results confirm those of Docherty and Ziemann that the OH scavenger plays a role in SOA formation in alkene ozonolysis. The extent and direction of this influence are shown to be dependent on the specific alkene. The main influence of the scavenger arises from its independent production of HO_2 radicals, with CO producing the most HO_2, 2-butanol an intermediate amount, and cyclohexane the least. This work provides evidence for the central role of acylperoxy radicals in SOA formation from the ozonolysis of alkenes and generally underscores the importance of gas-phase radical chemistry beyond the initial ozone-alkene reaction.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/es049725jDOIArticle
http://pubs.acs.org/doi/abs/10.1021/es049725jPublisherArticle
ORCID:
AuthorORCID
Flagan, R. C.0000-0001-5690-770X
Seinfeld, J. H.0000-0003-1344-4068
Additional Information:© 2004 American Chemical Society. Received for review February 20, 2004. Revised manuscript received April 7, 2004. Accepted April 13, 2004. Publication Date (Web): May 15, 2004. This research was supported by the Biological and Environmental Research Program (BER), U.S. Department of Energy Grant No. DE-FG03-01ER 63099, and U.S. Environmental Protection Agency Grant RD-831-07501-0. Although the research described in this article has been funded in part by the U.S. Environmental Protection Agency, it has not been subjected to the Agency's required peer and policy review and therefore does not necessarily reflect the views of the Agency and no official endorsement should be inferred.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-FG03-01ER 63099
Environmental Protection Agency (EPA)RD-831-07501-0
Issue or Number:12
Record Number:CaltechAUTHORS:20160614-162310887
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160614-162310887
Official Citation:Secondary Organic Aerosol Formation from Cyclohexene Ozonolysis:  Effect of OH Scavenger and the Role of Radical Chemistry M. D. Keywood, J. H. Kroll, V. Varutbangkul, R. Bahreini, R. C. Flagan, and J. H. Seinfeld Environmental Science & Technology 2004 38 (12), 3343-3350 DOI: 10.1021/es049725j
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:67926
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:15 Jun 2016 15:21
Last Modified:03 Oct 2019 10:09

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