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Modeling the Concentrations of Gas-Phase Toxic Organic Air Pollutants: Direct Emissions and Atmospheric Formation

Harley, Robert A. and Cass, Glen R. (1994) Modeling the Concentrations of Gas-Phase Toxic Organic Air Pollutants: Direct Emissions and Atmospheric Formation. Environmental Science and Technology, 28 (1). pp. 88-98. ISSN 0013-936X. https://resolver.caltech.edu/CaltechAUTHORS:20160629-121646464

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Abstract

An Eulerian photochemical air quality model is described for the prediction of the atmospheric transport and chemical reactions of gas-phase toxic organic air pollutants. Model performance was examined in the Los Angeles, CA, area over the period August 27-28, 1987. The organic compounds were drawn from a list of 189 species selected for control as hazardous air pollutants in the Clean Air Act amendments of 1990. The species considered include benzene, various alkylbenzenes, phenol, cresols, 1,3- butadiene, acrolein, formaldehyde, acetaldehyde, and perchloroethylene among others. It is found that photochemical generation contributes significantly to form-aldehyde, acetaldehyde, acetone, and acrolein concentrations for the 2-day period studied. Phenol concentrations are dominated by direct emissions, despite the existence of a pathway for atmospheric formation from benzene oxidation. The finding that photochemical production can be a major contributor to the total concentrations of some toxic organic species implies that control programs for those species must consider more than just direct emissions.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1021/es00050a013DOIArticle
http://pubs.acs.org/doi/abs/10.1021/es00050a013PublisherArticle
http://pubs.acs.org/doi/suppl/10.1021/es00050a013Related ItemSupporting Information
Additional Information:© 1993 American Chemical Society. Received for review March 25, 1993. Revised manuscript received September 9, 1993. Accepted September 13, 1993. The authors thank Dr. W. P. L. Carter of the University of California at Riverside for his assistance. This research was supported by the Electric Power Research Institute under Agreement RP3189-3.
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Funding AgencyGrant Number
Electric Power Research Institute (EPRI)RP3189-3
Issue or Number:1
Record Number:CaltechAUTHORS:20160629-121646464
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160629-121646464
Official Citation:Modeling the concentrations of gas-phase toxic organic air pollutants: direct emissions and atmospheric formation Robert A. Harley and Glen R. Cass Environmental Science & Technology 1994 28 (1), 88-98 DOI: 10.1021/es00050a013
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:68750
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:29 Jun 2016 20:56
Last Modified:03 Oct 2019 10:16

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