Russell, Armistead G. and Cass, Glen R. and Seinfeld, John H. (1986) On Some Aspects of Nighttime Atmospheric Chemistry. Environmental Science and Technology, 20 (11). pp. 1167-1172. ISSN 0013-936X. doi:10.1021/es00153a013. https://resolver.caltech.edu/CaltechAUTHORS:20160629-142631276
Full text is not posted in this repository. Consult Related URLs below.
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20160629-142631276
Abstract
Nighttime atmospheric chemistry is simulated in two different situations: an offshore oceanic environment, the Santa Barbara Channel region of the south central coast of California, and a dry environment, the Mojave Desert of California. In the marine case, conversion of NO_x to peroxyacetyl nitrate (PAN) and HNO_3 is rapid; HNO_3 is formed by homogeneous hydrolysis of N_2O_5 and by nitrate radical reactions with organic gases, and the rate of HNO_3 production is limited by the abundance of O_3. Even in the desert case, predictions indicate that homogeneous hydrolysis of N_2O_5 dominates HNO_3 formation at night. The implications of recent studies concerning the unimolecular decomposition of NO_3 are discussed.
Item Type: | Article | |||||||||
---|---|---|---|---|---|---|---|---|---|---|
Related URLs: |
| |||||||||
ORCID: |
| |||||||||
Additional Information: | © 1986 American Chemical Society. Received for review September 20, 1985. Revised manuscript received April 18, 1986. Accepted July 21, 1986. This project was funded, in part, by the California Air Resources Board under Agreement A2-150-32. We thank J. G. Calvert and H. Johnston for providing a preprint of their article and for a number of helpful comments on a draft of the manuscript. | |||||||||
Funders: |
| |||||||||
Issue or Number: | 11 | |||||||||
DOI: | 10.1021/es00153a013 | |||||||||
Record Number: | CaltechAUTHORS:20160629-142631276 | |||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160629-142631276 | |||||||||
Official Citation: | On some aspects of nighttime atmospheric chemistry Armistead G. Russell, Glen R. Cass, and John H. Seinfeld Environmental Science & Technology 1986 20 (11), 1167-1172 DOI: 10.1021/es00153a013 | |||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
ID Code: | 68765 | |||||||||
Collection: | CaltechAUTHORS | |||||||||
Deposited By: | Ruth Sustaita | |||||||||
Deposited On: | 29 Jun 2016 21:50 | |||||||||
Last Modified: | 11 Nov 2021 04:04 |
Repository Staff Only: item control page