Lee, I-Ren and Bañares, Luis and Zewail, Ahmed H. (2008) Direct Observation of the Primary Bond-Twisting Dynamics of Stilbene Anion Radical. Journal of the American Chemical Society, 130 (21). pp. 6708-6709. ISSN 0002-7863. doi:10.1021/ja801926m. https://resolver.caltech.edu/CaltechAUTHORS:20160816-095602727
![[img]](https://authors.library.caltech.edu/style/images/fileicons/application_pdf.png) |
PDF
- Supplemental Material
See Usage Policy. 36kB |
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20160816-095602727
Abstract
The anion radicals of stilbenes in the collisionless isolated phase were synthesized by electron attachment, and their dynamics were observed in real time on the femtosecond time scale. The observed coherent vibrational motion (∼42 cm^(−1)) and the primary bond-twisting dynamics (∼650 fs) for the D_2 state are on a vastly different time scale from that reported (∼10 ns) in solution.
| Item Type: | Article | ||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| Related URLs: |
| ||||||||||||
| Additional Information: | © 2008 American Chemical Society. Received March 14, 2008. Publication Date (Web): May 07, 2008. L.B. gratefully acknowledges Del Amo Foundation and Research Vice-rectorate (acción especial no. AE10/07-15604) of Universidad Complutense de Madrid for financial support of travel for a two months stay at Caltech and A.Z. for his hospitality. This work is supported by the National Science Foundation and the Air Force Office of Scientific Research. | ||||||||||||
| Funders: |
| ||||||||||||
| Issue or Number: | 21 | ||||||||||||
| DOI: | 10.1021/ja801926m | ||||||||||||
| Record Number: | CaltechAUTHORS:20160816-095602727 | ||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160816-095602727 | ||||||||||||
| Official Citation: | Direct Observation of the Primary Bond-Twisting Dynamics of Stilbene Anion Radical I-Ren Lee, Luis Bañares, and Ahmed H. Zewail Journal of the American Chemical Society 2008 130 (21), 6708-6709 DOI: 10.1021/ja801926m | ||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||
| ID Code: | 69654 | ||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||
| Deposited By: | Ruth Sustaita | ||||||||||||
| Deposited On: | 16 Aug 2016 21:09 | ||||||||||||
| Last Modified: | 11 Nov 2021 04:17 |
Repository Staff Only: item control page
