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The Transition State of Thermal Organic Reactions: Direct Observation in Real Time

Paik, D. Hern and Yang, Ding-Shyue and Lee, I-Ren and Zewail, Ahmed H. (2004) The Transition State of Thermal Organic Reactions: Direct Observation in Real Time. Angewandte Chemie International Edition, 43 (21). pp. 2830-2834. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20160817-092916634

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Abstract

A classic in physical organic chemistry, the inversion of cyclooctatetraene (COT), was studied with femtosecond resolution by negative-ion-beam techniques. The transition state for the thermal inversion was accessed directly by detachment of the electron from the planar COT− ion.


Item Type:Article
Related URLs:
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http://dx.doi.org/10.1002/anie.200453962DOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/anie.200453962/abstractPublisherArticle
Additional Information:© 2004 Wiley-VCH Verlag GmbH & Co. Received: February 6, 2004. Version of Record online: 28 Apr 2004. Financial support from the National Science Foundation is acknowledged.
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Funding AgencyGrant Number
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Subject Keywords:cyclooctatetraene, femtochemistry, photodetachment, transition states, wave-packet dynamics
Issue or Number:21
Record Number:CaltechAUTHORS:20160817-092916634
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160817-092916634
Official Citation:Paik, D. H., Yang, D.-S., Lee, I.-R. and Zewail, A. H. (2004), The Transition State of Thermal Organic Reactions: Direct Observation in Real Time. Angew. Chem. Int. Ed., 43: 2830–2834. doi: 10.1002/anie.200453962
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:69695
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:17 Aug 2016 22:01
Last Modified:03 Oct 2019 10:24

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