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The Presolvated Electron in Water: Can It Be Scavenged at Long Range?

Lu, Qing-Bin and Baskin, J. Spencer and Zewail, Ahmed H. (2004) The Presolvated Electron in Water: Can It Be Scavenged at Long Range? Journal of Physical Chemistry B, 108 (29). pp. 10509-10514. ISSN 1520-6106. doi:10.1021/jp0400824. https://resolver.caltech.edu/CaltechAUTHORS:20160817-092917457

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Abstract

Femtosecond transient absorption measurements were carried out to investigate the scavenging effect, at low concentration, of the radiosensitizing molecule 5-bromo-2‘-deoxyuridine (BrdU) on presolvation states of the hydrated electron. Hydrated electrons were generated by two photon absorption of bulk water at 267 nm, and transient absorption at 1200 nm was monitored. Results from experiments performed with the sample in a 5-mm cell showed a dramatic BrdU concentration dependence strongly suggestive of dynamic scavenging of the presolvated electron observable at concentrations as low as 0.2 mM, but no scavenging was detected in experiments on a thin sample jet with BrdU concentrations of up to 10 mM. Further analysis reconciled these results, confirming the absence of scavenging and attributing the concentration effect in the cell measurements to a group-velocity-dispersion-induced concentration dependence of the temporal response function. However, low concentrations of BrdU were seen to enhance the generation of hydrated electrons for excitation at both 267 and 310 nm.


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http://dx.doi.org/10.1021/jp0400824DOIArticle
http://pubs.acs.org/doi/abs/10.1021/jp0400824PublisherArticle
Additional Information:© 2004 American Chemical Society. Received: January 30, 2004. Publication Date (Web): April 3, 2004. This work was supported by the National Science Foundation.
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Issue or Number:29
DOI:10.1021/jp0400824
Record Number:CaltechAUTHORS:20160817-092917457
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160817-092917457
Official Citation:The Presolvated Electron in Water:  Can It Be Scavenged at Long Range? Qing-Bin Lu, J. Spencer Baskin, and, and Ahmed H. Zewail The Journal of Physical Chemistry B 2004 108 (29), 10509-10514 DOI: 10.1021/jp0400824
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:69698
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:17 Aug 2016 17:10
Last Modified:11 Nov 2021 04:18

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