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Ultrafast Electron Diffraction and Structural Dynamics: Transient Intermediates in the Elimination Reaction of C_2F_4I_2

Ihee, Hyotcherl and Goodson, Boyd M. and Srinivasan, Ramesh and Lobastov, Vladimir A. and Zewail, Ahmed H. (2002) Ultrafast Electron Diffraction and Structural Dynamics: Transient Intermediates in the Elimination Reaction of C_2F_4I_2. Journal of Physical Chemistry A, 106 (16). pp. 4087-4103. ISSN 1089-5639. doi:10.1021/jp014144r. https://resolver.caltech.edu/CaltechAUTHORS:20160818-082442438

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Abstract

We give a full account of our earlier report on the structural dynamics in the elimination reaction of C_2F_4I_2, as studied with the newly constructed third-generation apparatus for ultrafast electron diffraction (UED3) at Caltech (Ihee, H.; Lobastov, V. A.; Gomez, U., Goodson B. M.; Srinivasan, R.; Ruan, C.-Y.; Zewail, A. H. Science 2000, 291, 458). Improvements in experimental stability, sensitivity, resolution, and versatility provided by UED3 permitted the reaction to be probed with spatial and temporal resolution of ∼1 ps and ∼0.01 Å, respectively, and with a sensitivity to chemical change of ∼1%. In addition to the improvements in apparatus design, a number of advancements in data processing, analysis, and modeling were developed which are described here in detail for the first time. With UED, we directly observed the prompt (within 5 ps) formation of the C_2F_4I transient structure, and its subsequent decay with a rate of (25 ± 7 ps)^(-1). The molecular structure of the C_2F_4I radical was determined to be classical, not bridged-and was refined via a least-squares fitting procedure. These experimental results are compared with recent predictions obtained from ab initio and density functional theory calculations (Ihee, H.; Kua, J.; Goddard, W. A.; Zewail A. H. J. Phys. Chem. A 2001, 105, 3623), yielding quantitative agreement to within 0.03 Å between the experimental and theoretical structures for the transient intermediate.


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http://dx.doi.org/10.1021/jp014144rDOIArticle
http://pubs.acs.org/doi/abs/10.1021/jp014144rPublisherArticle
ORCID:
AuthorORCID
Goodson, Boyd M.0000-0001-6079-5077
Additional Information:© 2002 American Chemical Society. Received: November 12, 2001; In Final Form: February 25, 2002. Publication Date (Web): April 2, 2002. This work was supported by the National Science Foundation and the Air Force Office of Scientific Research. We gratefully acknowledge U. Gomez for his work in the primary construction of the UED3 apparatus. We also thank C.-Y. Ruan and D. Zhong for helpful discussions.
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Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Issue or Number:16
DOI:10.1021/jp014144r
Record Number:CaltechAUTHORS:20160818-082442438
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160818-082442438
Official Citation:Ultrafast Electron Diffraction and Structural Dynamics:  Transient Intermediates in the Elimination Reaction of C2F4I2 Hyotcherl Ihee, Boyd M. Goodson, Ramesh Srinivasan, Vladimir A. Lobastov, and Ahmed H. Zewail The Journal of Physical Chemistry A 2002 106 (16), 4087-4103 DOI: 10.1021/jp014144r
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:69747
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:18 Aug 2016 19:14
Last Modified:11 Nov 2021 04:19

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