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Ultrafast Electron Diffraction of Transient [Fe(CO)_4]: Determination of Molecular Structure and Reaction Pathway

Ihee, Hyotcherl and Cao, Jianming and Zewail, Ahmed H. (2001) Ultrafast Electron Diffraction of Transient [Fe(CO)_4]: Determination of Molecular Structure and Reaction Pathway. Angewandte Chemie International Edition, 40 (8). pp. 1532-1536. ISSN 1433-7851. https://resolver.caltech.edu/CaltechAUTHORS:20160819-085641985

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Abstract

The temporal diffraction–difference approach of the ultrafast electron diffraction (UED) technique was used to determine the molecular structure of the transient [Fe(CO)_4] (see picture) formed during the elimination of CO ligands from [Fe(CO)_5]. The results clearly show that the major product, up to 200 ps, is the transient [Fe(CO)_4] which is formed in the ^1A_1 state, rather than the ground ^3B_2 state.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1002/1521-3773(20010417)40:8<1532::AID-ANIE1532>3.0.CO;2-EDOIArticle
http://onlinelibrary.wiley.com/doi/10.1002/1521-3773(20010417)40:8%3C1532::AID-ANIE1532%3E3.0.CO;2-E/abstractPublisherArticle
Additional Information:© 2001 Wiley-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany. Received: December 29, 2000. Version of Record online: 17 Apr 2001. This work was supported by grants from the National Science Foundation, Air Force Office of Scientific Research, and the Office of Naval Research.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Office of Naval Research (ONR)UNSPECIFIED
Issue or Number:8
Record Number:CaltechAUTHORS:20160819-085641985
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160819-085641985
Official Citation:Ihee, H., Cao, J. and Zewail, A. H. (2001), Ultrafast Electron Diffraction of Transient [Fe(CO)4]: Determination of Molecular Structure and Reaction Pathway . Angew. Chem. Int. Ed., 40: 1532–1536. doi: 10.1002/1521-3773(20010417)40:8<1532::AID-ANIE1532>3.0.CO;2-E
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:69776
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:23 Aug 2016 18:13
Last Modified:03 Oct 2019 10:25

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