Ihee, Hyotcherl and Cao, Jianming and Zewail, Ahmed H. (2001) Ultrafast Electron Diffraction of Transient [Fe(CO)_4]: Determination of Molecular Structure and Reaction Pathway. Angewandte Chemie International Edition, 40 (8). pp. 1532-1536. ISSN 1433-7851. doi:10.1002/1521-3773(20010417)40:8<1532::AID-ANIE1532>3.0.CO;2-E. https://resolver.caltech.edu/CaltechAUTHORS:20160819-085641985
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Abstract
The temporal diffraction–difference approach of the ultrafast electron diffraction (UED) technique was used to determine the molecular structure of the transient [Fe(CO)_4] (see picture) formed during the elimination of CO ligands from [Fe(CO)_5]. The results clearly show that the major product, up to 200 ps, is the transient [Fe(CO)_4] which is formed in the ^1A_1 state, rather than the ground ^3B_2 state.
| Item Type: | Article | |||||||||
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| Additional Information: | © 2001 Wiley-VCH Verlag GmbH, Weinheim, Fed. Rep. of Germany. Received: December 29, 2000. Version of Record online: 17 Apr 2001. This work was supported by grants from the National Science Foundation, Air Force Office of Scientific Research, and the Office of Naval Research. | |||||||||
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| Issue or Number: | 8 | |||||||||
| DOI: | 10.1002/1521-3773(20010417)40:8<1532::AID-ANIE1532>3.0.CO;2-E | |||||||||
| Record Number: | CaltechAUTHORS:20160819-085641985 | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20160819-085641985 | |||||||||
| Official Citation: | Ihee, H., Cao, J. and Zewail, A. H. (2001), Ultrafast Electron Diffraction of Transient [Fe(CO)4]: Determination of Molecular Structure and Reaction Pathway . Angew. Chem. Int. Ed., 40: 1532–1536. doi: 10.1002/1521-3773(20010417)40:8<1532::AID-ANIE1532>3.0.CO;2-E | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 69776 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Ruth Sustaita | |||||||||
| Deposited On: | 23 Aug 2016 18:13 | |||||||||
| Last Modified: | 11 Nov 2021 04:19 |
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