CaltechAUTHORS
  A Caltech Library Service

Femtochemistry in nanocavities: dissociation, recombination and vibrational cooling of iodine in cyclodextrin

Chachisvilis, M. and Garcia-Ochoa, I. and Douhal, A. and Zewail, A. H. (1998) Femtochemistry in nanocavities: dissociation, recombination and vibrational cooling of iodine in cyclodextrin. Chemical Physics Letters, 293 (3-4). pp. 153-159. ISSN 0009-2614. https://resolver.caltech.edu/CaltechAUTHORS:20160823-144514120

Full text is not posted in this repository. Consult Related URLs below.

Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:20160823-144514120

Abstract

We report studies of the femtosecond dynamics of reactions in confined nanocavities in water solutions. In an earlier publication [J. Phys. Chem. A 102 (1998) 1657] we reported studies of proton transfer and isomerization in these media. Here, we examine the elementary processes of dissociation, recombination and vibrational relaxation of the guest iodine molecule encapsulated into the cavity of cyclodextrin (diameter ∼8 Å). For comparison, the relaxation dynamics of the same guest in tetrahydrofuran and in pure water were also studied.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/S0009-2614(98)00751-9DOIArticle
http://www.sciencedirect.com/science/article/pii/S0009261498007519PublisherArticle
Additional Information:© 1998 Elsevier Science B.V. Received 2 June 1998; in final form 22 June 1998. Available online 16 September 1998. This work was supported by the National Science Foundation. MC thanks the Swedish Foundation for International Cooperation in Research and Higher Education (STINT) for financial support. MC is the recepient of a post-doctoral fellowship from the Swedish Foundation for International Cooperation in Research and Higher Education. IG-M also thanks the "Comunidad de Castilla-La Mancha' (Spain) for a doctoral fellowship.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
Swedish Foundation for International Cooperation in Research and Higher Education (STINT)UNSPECIFIED
Comunidad de Castilla-La ManchaUNSPECIFIED
Issue or Number:3-4
Record Number:CaltechAUTHORS:20160823-144514120
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160823-144514120
Official Citation:M Chachisvilis, I Garcia-Ochoa, A Douhal, A.H Zewail, Femtochemistry in nanocavities: dissociation, recombination and vibrational cooling of iodine in cyclodextrin, Chemical Physics Letters, Volume 293, Issues 3–4, 28 August 1998, Pages 153-159, ISSN 0009-2614, http://dx.doi.org/10.1016/S0009-2614(98)00751-9. (http://www.sciencedirect.com/science/article/pii/S0009261498007519)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:69857
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:23 Aug 2016 23:28
Last Modified:03 Oct 2019 10:26

Repository Staff Only: item control page