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Femtosecond Nucleophilic Substitution Reaction Dynamics

Zhong, D. and Ahmad, S. and Cheng, P. Y. and Zewail, A. H. (1997) Femtosecond Nucleophilic Substitution Reaction Dynamics. Journal of the American Chemical Society, 119 (9). pp. 2305-2306. ISSN 0002-7863. https://resolver.caltech.edu/CaltechAUTHORS:20160824-074504153

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Abstract

A general class of reactions termed aromatic nucleophilic substitution (S_NAr) is central to organic syntheses, reaction mechanisms, and electron transfer processes. A textbook example is the following reaction which is generally considered as a two-step process, the addition of the nucleophile (a → b) and the elimination to form final products (b → c). However, if the processes of addition and elimination are concerted, the so-called σ-complex (b) becomes a transition state, similar in nature to S_N2 reactions.


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http://dx.doi.org/10.1021/ja963879kDOIArticle
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Additional Information:© 1997 American Chemical Society. Received November 8, 1996. Publication Date (Web): March 5, 1997. This work was supported by a grant from the National Science Foundation.
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Issue or Number:9
Record Number:CaltechAUTHORS:20160824-074504153
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20160824-074504153
Official Citation:Femtosecond Nucleophilic Substitution Reaction Dynamics D. Zhong, S. Ahmad, P. Y. Cheng, and A. H. Zewail Journal of the American Chemical Society 1997 119 (9), 2305-2306 DOI: 10.1021/ja963879k
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:69877
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:26 Aug 2016 18:08
Last Modified:03 Oct 2019 10:26

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